Home / Publications / Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines

Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines

, 
Tatyana Leonidovna Lizunova 1
Tatyana Leonidovna Lizunova
, 
Bogdan Ivanovich Ugrak 1
Bogdan Ivanovich Ugrak
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1070/MC1993v003n05ABEH000282
Published 1993-10-30
Communication , Volume 3, Issue 5, 191-192
8
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Elinson M. N. et al. Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 191-192.
GOST all authors (up to 50) Copy
Elinson M. N., Lizunova T. L., Ugrak B. I., Nikishin G. I. Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 191-192.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1993v003n05ABEH000282
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000282
TI - Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines
T2 - Mendeleev Communications
AU - Elinson, Michail Nikolaevich
AU - Lizunova, Tatyana Leonidovna
AU - Ugrak, Bogdan Ivanovich
AU - Nikishin, Gennady Ivanovich
PY - 1993
DA - 1993/10/30
PB - Mendeleev Communications
SP - 191-192
IS - 5
VL - 3
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Elinson,
author = {Michail Nikolaevich Elinson and Tatyana Leonidovna Lizunova and Bogdan Ivanovich Ugrak and Gennady Ivanovich Nikishin},
title = {Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000282},
number = {5},
pages = {191--192},
doi = {10.1070/MC1993v003n05ABEH000282}
}
MLA
Cite this
MLA Copy
Elinson, Michail Nikolaevich, et al. “Electrochemical Transformation of Malononitrile and Aldehydes into 3-Substituted 1,1,2,2-Tetracyanocyclopropanes and Bicyclic Pyrrolines.” Mendeleev Communications, vol. 3, no. 5, Oct. 1993, pp. 191-192. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000282.

Abstract

Electrolysis of malononitrile in the presence of aldehydes and NaBr in alcohols in the undivided cell results in the formation of 3-substituted 1,1,2,2-tetracyanocyclopropanes or 6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes, depending on the nature of the aldehydes and the quantity of electricity passed.

References

3.
Electrochemical cyclodimerization of alkylidenemalonates into 3,4-disubstituted cyclobutane-1,1,2,2-tetracarboxylates
Nikishin G.I., Elinson M.N., Feducovich S.K., Ugrak B.I., Struchkov Y.T., Lindeman S.V.
Tetrahedron Letters, 1992
5.
Elinson M.N., Lizunova T.L., Ugrak B.I., Lindeman S.V., Dekaprilevich M.O., Turdybekov K.M., Struchkov Y.T., Nikishin G.I.
Mendeleev Communications, 1993