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Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids

Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Stanislav Zbignevovich Bernadyuk 1
Stanislav Zbignevovich Bernadyuk
, 
Mark Efimovich Vol'pin 1
Mark Efimovich Vol'pin
10.1070/MC1993v003n05ABEH000280
Published 1993-10-30
Communication , Volume 3, Issue 5, 188-189
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Akhrem I. S., Bernadyuk S. Z., Vol'pin M. E. Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 188-189.
GOST all authors (up to 50) Copy
Akhrem I. S., Bernadyuk S. Z., Vol'pin M. E. Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids // Mendeleev Communications. 1993. Vol. 3. No. 5. pp. 188-189.
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TY - JOUR
DO - 10.1070/MC1993v003n05ABEH000280
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000280
TI - Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids
T2 - Mendeleev Communications
AU - Akhrem, Irena Sergeevna
AU - Bernadyuk, Stanislav Zbignevovich
AU - Vol'pin, Mark Efimovich
PY - 1993
DA - 1993/10/30
PB - Mendeleev Communications
SP - 188-189
IS - 5
VL - 3
ER -
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@article{1993_Akhrem,
author = {Irena Sergeevna Akhrem and Stanislav Zbignevovich Bernadyuk and Mark Efimovich Vol'pin},
title = {Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000280},
number = {5},
pages = {188--189},
doi = {10.1070/MC1993v003n05ABEH000280}
}
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Akhrem, Irena Sergeevna, et al. “Carbonylation of Cyclopentane in the Presence of Aprotic Organic Superacids.” Mendeleev Communications, vol. 3, no. 5, Oct. 1993, pp. 188-189. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n05ABEH000280.

Abstract

The systems MeCOBr·nAlBr3 as well as CHBr3·nAlBr3 and CCl4·nAlBr3 (n =1-4.5) have been shown to initiate carbonylation of cyclopentane under mild conditions to give, after alcoholic work-up, the corresponding ester of cyclopentylcarboxylic acid with good yields and high selectivity.

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