Home / Publications / The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System)

The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System)

Olga Ivanovna Danilova 1
Olga Ivanovna Danilova
, 
Sergei Samoilovich Yufit 1
Sergei Samoilovich Yufit
10.1070/MC1993v003n04ABEH000271
Published 1993-08-31
Communication , Volume 3, Issue 4, 165-166
6
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Danilova O. I., Yufit S. S. The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System) // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 165-166.
GOST all authors (up to 50) Copy
Danilova O. I., Yufit S. S. The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System) // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 165-166.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1993v003n04ABEH000271
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000271
TI - The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System)
T2 - Mendeleev Communications
AU - Danilova, Olga Ivanovna
AU - Yufit, Sergei Samoilovich
PY - 1993
DA - 1993/08/31
PB - Mendeleev Communications
SP - 165-166
IS - 4
VL - 3
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Danilova,
author = {Olga Ivanovna Danilova and Sergei Samoilovich Yufit},
title = {The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System)},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000271},
number = {4},
pages = {165--166},
doi = {10.1070/MC1993v003n04ABEH000271}
}
MLA
Cite this
MLA Copy
Danilova, Olga Ivanovna, and Sergei Samoilovich Yufit. “The Effect of Solvents on SN2 Substitution under Phase-transfer Catalysis (Liquid/Solid System).” Mendeleev Communications, vol. 3, no. 4, Aug. 1993, pp. 165-166. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000271.

Abstract

Substitution in a two-phase system containing a solid ionophore in the present of a phase-transfer catalyst is accelerated by an increase in the Lewis basicity (measured by the donor number DN) and poiarizability (P) and is inhibited by an increase in the Lewis acidity, measured by the acceptor number (AN) of the solvent

References

1.
10.1070/MC1993v003n04ABEH000271_bib1
Dehmlow
Phase Transfer Catalysis, 1992
2.
10.1070/MC1993v003n04ABEH000271_bib2
Antoine
Bull. Soc. Chim. Fr., 1980
3.
10.1070/MC1993v003n04ABEH000271_bib3
Yufit
Dokl. Akad. Nauk SSSR, 1987
5.
10.1070/MC1993v003n04ABEH000271_bib5
Danilova
Izv. Akad. Nauk SSSR, Ser. Khim., 1986
6.
10.1070/MC1993v003n04ABEH000271_bib6
Weissberger
Organic Solvents, 1955
7.
10.1070/MC1993v003n04ABEH000271_bib7
Schmid
Non-formal Kinetics, 1982
8.
New ideas on phase transfer catalysts: SN2 reaction with a solid ionophoric salt
Yufit S.S., Esikova I.A.
Journal of Physical Organic Chemistry, 1991
10.
10.1070/MC1993v003n04ABEH000271_bib10
Koppel
The Influence of the Solvent on Organic Reactivity, in Advances in Linear Free Energy Relationships, 1972