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Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer

Elena Mikhailovna Koldasheva 1
Elena Mikhailovna Koldasheva
, 
Yurii Vasil'evich Geletii 2
Yurii Vasil'evich Geletii
, 
Alexander Fedorovich Shestakov 1
Alexander Fedorovich Shestakov
, 
Alexander Vasilyvich Kulikov 1
Alexander Vasilyvich Kulikov
, 
Aleksandr Evgen'evich Shilov 3
Aleksandr Evgen'evich Shilov
10.1070/MC1993v003n04ABEH000258
Published 1993-08-31
Communication , Volume 3, Issue 4, 142-143
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Koldasheva E. M. et al. Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 142-143.
GOST all authors (up to 50) Copy
Koldasheva E. M., Geletii Y. V., Shestakov A. F., Kulikov A. V., Shilov A. E. Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 142-143.
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TY - JOUR
DO - 10.1070/MC1993v003n04ABEH000258
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000258
TI - Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer
T2 - Mendeleev Communications
AU - Koldasheva, Elena Mikhailovna
AU - Geletii, Yurii Vasil'evich
AU - Shestakov, Alexander Fedorovich
AU - Kulikov, Alexander Vasilyvich
AU - Shilov, Aleksandr Evgen'evich
PY - 1993
DA - 1993/08/31
PB - Mendeleev Communications
SP - 142-143
IS - 4
VL - 3
ER -
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@article{1993_Koldasheva,
author = {Elena Mikhailovna Koldasheva and Yurii Vasil'evich Geletii and Alexander Fedorovich Shestakov and Alexander Vasilyvich Kulikov and Aleksandr Evgen'evich Shilov},
title = {Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000258},
number = {4},
pages = {142--143},
doi = {10.1070/MC1993v003n04ABEH000258}
}
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Koldasheva, Elena Mikhailovna, et al. “Phenazine Di-N-toxide Radical Cation Reactions with Secondary Amines. Evidence for Oxygen Cation Transfer.” Mendeleev Communications, vol. 3, no. 4, Aug. 1993, pp. 142-143. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000258.

Abstract

A novel reaction involving O+ transfer from phenazine di-N-oxide radical cation (OPO+.) to secondary amines to form phenazine mono-N-oxide (OP) and nitroxyl radical has been observed and investigated by cyclic voltammetry and EPR methods.

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