Home / Publications / Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes

Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes

Alexander Mikhailovich Khenkin 1
Alexander Mikhailovich Khenkin
, 
Craig L Hill 2
Craig L Hill
10.1070/MC1993v003n04ABEH000257
Published 1993-08-31
Communication , Volume 3, Issue 4, 140-141
37
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Khenkin A. M., Hill C. L. Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 140-141.
GOST all authors (up to 50) Copy
Khenkin A. M., Hill C. L. Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 140-141.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1993v003n04ABEH000257
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000257
TI - Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes
T2 - Mendeleev Communications
AU - Khenkin, Alexander Mikhailovich
AU - Hill, Craig L
PY - 1993
DA - 1993/08/31
PB - Mendeleev Communications
SP - 140-141
IS - 4
VL - 3
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1993_Khenkin,
author = {Alexander Mikhailovich Khenkin and Craig L Hill},
title = {Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000257},
number = {4},
pages = {140--141},
doi = {10.1070/MC1993v003n04ABEH000257}
}
MLA
Cite this
MLA Copy
Khenkin, Alexander Mikhailovich, and Craig L Hill. “Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes.” Mendeleev Communications, vol. 3, no. 4, Aug. 1993, pp. 140-141. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000257.

Abstract

The d-election transition metal-substituted heteropolytungstate sandwich complex [(FeII)4(B–PW9O34)2]10−, unlike PW12O403− and most polytungstophosphates, is quite stable with respect to solvolysis by H2O2 and catalyses the selective homogeneous epoxidation of alkenes in aqueous acetonitrile at 20°C by this oxidant.

References

1.
10.1070/MC1993v003n04ABEH000257_bib1
Catalytic Oxidations with Hydrogen Peroxide as Oxidant, 1992
2.
10.1070/MC1993v003n04ABEH000257_bib2
Activation of Saturated Hydrocarbons by Transition Metal Complexes, 1984
3.
10.1070/MC1993v003n04ABEH000257_bib3
Activation, Functionalization of Alkanes, 1989
4.
10.1070/MC1993v003n04ABEH000257_bib4
Selective Hydrocarbon Activation. Principles and Progress, 1990
7.
Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [PMO12O40]3-[C5H5N+(CH2)15CH3]3
Matoba Y., Inoue H., Akagi J., Okabayashi T., Ishii Y., Ogawa M.
Synthetic Communications, 1984
8.
10.1070/MC1993v003n04ABEH000257_bib6_2
Ishii
1990
9.
Reinvestigation of epoxidation using tungsten-based precursors and hydrogen peroxide in a biphase medium
Aubry C., Chottard G., Platzer N., Bregeault J.M., Thouvenot R., Chauveau F., Huet C., Ledon H.
Inorganic Chemistry, 1991
11.
10.1070/MC1993v003n04ABEH000257_bib8_1
Khenkin
New J. Chem., 1989
12.
Models for non-heme iron oxygenases: a high-valent iron-oxo intermediate
Leising R.A., Brennan B.A., Que L., Fox B.G., Munck E.
Journal of the American Chemical Society, 1991
16.
10.1070/MC1993v003n04ABEH000257_bib12
Sheldon
Metal-Catalysed Oxidations of Organic Compounds, 1981
17.
Mechanism of asymmetric epoxidation. 1. Kinetics
Woodard S.S., Finn M.G., Sharpless K.B.
Journal of the American Chemical Society, 1991
18.
Mechanism of asymmetric epoxidation. 2. Catalyst structure
Finn M.G., Sharpless K.B.
Journal of the American Chemical Society, 1991