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Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis

Nikolai Nikolaevich Buravtsev 1
Nikolai Nikolaevich Buravtsev
, 
Lev Solomonovich German 2
Lev Solomonovich German
, 
Alexander Stepanovich Grigor'ev 1
Alexander Stepanovich Grigor'ev
, 
Yuly Abramovich Kolbanovskii 1
Yuly Abramovich Kolbanovskii
, 
Anatoly Aleksandrovich Ovsyannikov 1
Anatoly Aleksandrovich Ovsyannikov
, 
Andrei Yuryevich Volkonsky 2
Andrei Yuryevich Volkonsky
10.1070/MC1993v003n04ABEH000254
Published 1993-08-31
Communication , Volume 3, Issue 4, 133-134
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Buravtsev N. N. et al. Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 133-134.
GOST all authors (up to 50) Copy
Buravtsev N. N., German L. S., Grigor'ev A. S., Kolbanovskii Y. A., Ovsyannikov A. A., Volkonsky A. Y. Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis // Mendeleev Communications. 1993. Vol. 3. No. 4. pp. 133-134.
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TY - JOUR
DO - 10.1070/MC1993v003n04ABEH000254
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000254
TI - Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis
T2 - Mendeleev Communications
AU - Buravtsev, Nikolai Nikolaevich
AU - German, Lev Solomonovich
AU - Grigor'ev, Alexander Stepanovich
AU - Kolbanovskii, Yuly Abramovich
AU - Ovsyannikov, Anatoly Aleksandrovich
AU - Volkonsky, Andrei Yuryevich
PY - 1993
DA - 1993/08/31
PB - Mendeleev Communications
SP - 133-134
IS - 4
VL - 3
ER -
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@article{1993_Buravtsev,
author = {Nikolai Nikolaevich Buravtsev and Lev Solomonovich German and Alexander Stepanovich Grigor'ev and Yuly Abramovich Kolbanovskii and Anatoly Aleksandrovich Ovsyannikov and Andrei Yuryevich Volkonsky},
title = {Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000254},
number = {4},
pages = {133--134},
doi = {10.1070/MC1993v003n04ABEH000254}
}
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Buravtsev, Nikolai Nikolaevich, et al. “Trifluoromethylfluorocarbene Formation and Reactions under C2F5SiF3 Pulsed Adiabatic Compression Pyrolysis.” Mendeleev Communications, vol. 3, no. 4, Aug. 1993, pp. 133-134. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n04ABEH000254.

Abstract

The formation of :CFCF3, SiF4 and (cis+trans)-2-C4F8 is demonstrated under the strictly homogeneous pyrolysis of C2F5SiF3, using kinetic spectroscopy (at 250 and 465 nm) and chromatographic analysis, respectively. Pyrolysis of 2-C4F8 under the same conditions leads to the formation of an intermediate (C4)* which reveals absorption at 250 nm.

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