Abstract
We have shown that the reaction BCl3+NH3→Cl2BNH2+HCl takes place in the gas phase at 70 °C and pressure < 1 Torr at the rate of collision between the molecules; the essential role of donor–acceptor interactions in the dynamics and kinetics of similar reactions is suggested.
References
1.
Legon A.C., Warner H.E.
Journal of the Chemical Society Chemical Communications,
1991
2.
Garvin D., Kistiakowsky G.B.
Journal of Chemical Physics,
1952
3.
Garvin D., Guinn V.P., Kistiakowsky G.B.
Discussions of the Faraday Society,
1954
4.
Kistiakowsky G.B., Zinman W.G.
Journal of Chemical Physics,
1955
5.
Smith F.T., Kistiakowsky G.B.
Journal of Chemical Physics,
1959
6.
Daen J., Marcus R.A.
Journal of Chemical Physics,
1957
7.
Glicker S., Marcus R.A.
Journal of the American Chemical Society,
1969
8.
Carpenter J.D., Ault B.S.
The Journal of Physical Chemistry,
1991
9.
10.1070/MC1993v003n03ABEH000251_bib5
Kapralova
Khimicheskaya Fizika,
1987
10.
10.1070/MC1993v003n03ABEH000251_bib6
Polanji
Atomic Reactions,
1932
11.
10.1070/MC1993v003n03ABEH000251_bib7
Brin
Khimicheskaya Fizika,
1991
12.
10.1070/MC1993v003n03ABEH000251_bib8
Robinson
Unimolecular Reactions,
1972
13.
10.1070/MC1993v003n03ABEH000251_bib9
Kondratiev
Termicheskie bimolekulyamye reaktsii v gazakhnl,
1976
14.
Brown C.A., Osthoff R.C.
Journal of the American Chemical Society,
1952