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Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide

Mikhail Mikhailovich Krayushkin 1
Mikhail Mikhailovich Krayushkin
, 
Marina Aleksandrovna Kalik 1
Marina Aleksandrovna Kalik
, 
Elena Yuryevna Zvezdina 1
Elena Yuryevna Zvezdina
, 
Lyudmila Grigor'evna Vorontsova 1
Lyudmila Grigor'evna Vorontsova
, 
Marina Gregorovna Kurella 1
Marina Gregorovna Kurella
10.1070/MC1993v003n03ABEH000249
Published 1993-06-30
Communication , Volume 3, Issue 3, 114-115
5
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Krayushkin M. M. et al. Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 114-115.
GOST all authors (up to 50) Copy
Krayushkin M. M., Kalik M. A., Zvezdina E. Y., Vorontsova L. G., Kurella M. G. Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 114-115.
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TY - JOUR
DO - 10.1070/MC1993v003n03ABEH000249
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000249
TI - Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide
T2 - Mendeleev Communications
AU - Krayushkin, Mikhail Mikhailovich
AU - Kalik, Marina Aleksandrovna
AU - Zvezdina, Elena Yuryevna
AU - Vorontsova, Lyudmila Grigor'evna
AU - Kurella, Marina Gregorovna
PY - 1993
DA - 1993/06/30
PB - Mendeleev Communications
SP - 114-115
IS - 3
VL - 3
ER -
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@article{1993_Krayushkin,
author = {Mikhail Mikhailovich Krayushkin and Marina Aleksandrovna Kalik and Elena Yuryevna Zvezdina and Lyudmila Grigor'evna Vorontsova and Marina Gregorovna Kurella},
title = {Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000249},
number = {3},
pages = {114--115},
doi = {10.1070/MC1993v003n03ABEH000249}
}
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Krayushkin, Mikhail Mikhailovich, et al. “Synthesis and Structure of New Derivatives of Thieno[2,3–b]thiocine. Unusual Intramolecular Cycloaddition Product of 2-Homomethallyl-3-thiophenecarbonitrile Oxide.” Mendeleev Communications, vol. 3, no. 3, Jun. 1993, pp. 114-115. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000249.

Abstract

For the first time 9-methyl-3,3a,4,5,6-hexahydrothieno[2,3-b]thiocine[4,5-c]isoxazole and 9-methyl-7-hydroxyimino-3,4,6-hexahydro-5-methylenethieno[2,3–b]thiocine have been prepared by NaOCl oxidation of 2-ω-alkenylthio-3-thiophenecarbaldoximes. The structure of these products has been confirmed by mass, 1H NMR and 13C NMR spectroscopy, and of the second, also by X-ray analysis.

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