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Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers

Èmmanuil Iosifovich Troyanskii 1
Èmmanuil Iosifovich Troyanskii
,  , 
Rustem F Ismagilov 2
Rustem F Ismagilov
, 
Margarita Ivanovna Lazareva 1
Margarita Ivanovna Lazareva
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1070/MC1993v003n03ABEH000248
Published 1993-06-30
Communication , Volume 3, Issue 3, 112-114
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Troyanskii È. I. et al. Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 112-114.
GOST all authors (up to 50) Copy
Troyanskii È. I., Demchuk D. V., Ismagilov R. F., Lazareva M. I., Strelenko Y. A., Nikishin G. I. Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 112-114.
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TY - JOUR
DO - 10.1070/MC1993v003n03ABEH000248
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000248
TI - Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers
T2 - Mendeleev Communications
AU - Troyanskii, Èmmanuil Iosifovich
AU - Demchuk, Dmitry Valentinovich
AU - Ismagilov, Rustem F
AU - Lazareva, Margarita Ivanovna
AU - Strelenko, Yurii Andreevich
AU - Nikishin, Gennady Ivanovich
PY - 1993
DA - 1993/06/30
PB - Mendeleev Communications
SP - 112-114
IS - 3
VL - 3
ER -
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@article{1993_Troyanskii,
author = {Èmmanuil Iosifovich Troyanskii and Dmitry Valentinovich Demchuk and Rustem F Ismagilov and Margarita Ivanovna Lazareva and Yurii Andreevich Strelenko and Gennady Ivanovich Nikishin},
title = {Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000248},
number = {3},
pages = {112--114},
doi = {10.1070/MC1993v003n03ABEH000248}
}
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Troyanskii, Èmmanuil Iosifovich, et al. “Homolytic Macrocyclization of Alkynes with Propane-1,3-dithiol as a Route to 14- and 21-Membered Crown Thioethers.” Mendeleev Communications, vol. 3, no. 3, Jun. 1993, pp. 112-114. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000248.

Abstract

Crown thioethers, 1,4,8,11-tetrathiacyclotetradecanes and 1,4,8,11,15,18-hexathiaheneicosanes, have been synthesized as 2:2 and 3:3 cycloadducts in a ‘one-pot’ homolytic macrocyclization of alkynes with propane-1,3-dithiol.

References

1.
Thermodynamic and kinetic data for cation-macrocycle interaction
Izatt R.M., Bradshaw J.S., Nielsen S.A., Lamb J.D., Christensen J.J., Sen D.
Chemical Reviews, 1985
3.
Synthesis of mesocyclic and macrocyclic polythioethers using the cesium dithiolate technique
Setzer W.N., Afshar S., Burns N.L., Ferrante L.A., Hester A.M., Meehan E.J., Grant G.J., Isaac S.M., Laudeman C.P., Lewis C.M., VanDerveer D.G.
Heteroatom Chemistry, 1990
4.
Regioselectivity and diastereoselectivity in free-radical macrocyclization
Porter N.A., Lacher B., Chang V.H., Magnin D.R.
Journal of the American Chemical Society, 1989
6.
10.1070/MC1993v003n03ABEH000248_bib6_1
Demchuk
Izv. Akad. Nauk SSSR, Ser. Khim., 1990
7.
10.1070/MC1993v003n03ABEH000248_bib6_2
Troyansky
Izv. Akad. Nauk SSSR, Ser. Khim., 1991
8.
SOME NEW HOMOLYTIC HETEROCYCLIZATION REACTIONS IN CHEMISTRY OF BIVALENT SULFUR COMPOUNDS
Nikishin G.I., Troyansky E.I., Demchuk D.V.
Phosphorus, Sulfur and Silicon and the Related Elements, 1991
9.
Troyansky E.I., Demchuk D.V., Lazareva M.I., Samoshin V.V., Strelenko Y.A., Nikishin G.I.
Mendeleev Communications, 1992
10.
Free Radical Intermolecular Macrocyclization: An Extremely Facile Route to 12-Membered Thiacrown Ethers
Troyansky E.I., Lazareva M.I., Demchuk D.V., Samoshin V.V., Strelenko Y.A., Nikishin G.I.
Synlett, 1992
11.
Nickel(II) complexes of cyclic tetradentate thioethers
Rosen W., Busch D.H.
Journal of the American Chemical Society, 1969