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N-Amination of Pyrazoles: a General Approach

Vasilii Mikhailovich Vinogradov 1
Vasilii Mikhailovich Vinogradov
Igor L'vovich Dalinger 1
Igor L'vovich Dalinger
Svyatoslav Arkad'evich Shevelev 1
Svyatoslav Arkad'evich Shevelev
Published 1993-06-30
CommunicationVolume 3, Issue 3, 111-111
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Vinogradov V. M., Dalinger I. L., Shevelev S. A. N-Amination of Pyrazoles: a General Approach // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 111-111.
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Vinogradov V. M., Dalinger I. L., Shevelev S. A. N-Amination of Pyrazoles: a General Approach // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 111-111.
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TY - JOUR
DO - 10.1070/MC1993v003n03ABEH000247
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000247
TI - N-Amination of Pyrazoles: a General Approach
T2 - Mendeleev Communications
AU - Vinogradov, Vasilii Mikhailovich
AU - Dalinger, Igor L'vovich
AU - Shevelev, Svyatoslav Arkad'evich
PY - 1993
DA - 1993/06/30
PB - Mendeleev Communications
SP - 111-111
IS - 3
VL - 3
ER -
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@article{1993_Vinogradov,
author = {Vasilii Mikhailovich Vinogradov and Igor L'vovich Dalinger and Svyatoslav Arkad'evich Shevelev},
title = {N-Amination of Pyrazoles: a General Approach},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000247},
number = {3},
pages = {111--111},
doi = {10.1070/MC1993v003n03ABEH000247}
}
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Vinogradov, Vasilii Mikhailovich, et al. “N-Amination of Pyrazoles: a General Approach.” Mendeleev Communications, vol. 3, no. 3, Jun. 1993, pp. 111-111. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000247.

Abstract

A general approach to N-amination of pyrazoles, allowing the synthesis of previously inaccessible N-aminopyrazoles with electron-acceptor substituents in the ring, has been proposed, consisting of treatment of the pyrazoles with hydroxylamine-O-sulfonic acid in aqueous media at controlled pH depending on pKa of the pyrazole.

References

1.
1,2,3-Triazine, III Synthese vonN-Aminopyrazolen und deren Oxidation zu 1,2,3-Triazinen. Molekülstruktur des 1,2,3-Triazins
Neunhoeffer H., Clausen M., Vötter H., Ohl H., Krüger C., Angermund K.
European Journal of Organic Chemistry, 1985
2.
Synthesis, oxidation, and reduction of monocyclic 1,2,3-triazines
Ohsawa A., Arai H., Ohnishi H., Igeta H.
Journal of the Chemical Society Chemical Communications, 1980
3.
R. J. Harder, US Pat., 3207763, 1965 (Chem. Abstr., 1965, 63,18096c.)
4.
Bildung von Diimid durch Aminierungsreaktionen
Schmitz E., Ohme R., Kozakiewicz G.
Zeitschrift fur Anorganische und Allgemeine Chemie, 1965
5.
10.1070/MC1993v003n03ABEH000247_bib5
Catalan
1987