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Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid

Boris Arnol'dovich Cheskis 1
Boris Arnol'dovich Cheskis
, 
Ivan Gennadievich Alekseev 1
Ivan Gennadievich Alekseev
, 
Aiexsander Makarovich Moiseenkov 1
Aiexsander Makarovich Moiseenkov
10.1070/MC1993v003n03ABEH000238
Published 1993-06-30
Communication , Volume 3, Issue 3, 93-96
5
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Cheskis B. A., Alekseev I. G., Moiseenkov A. M. Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 93-96.
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Cheskis B. A., Alekseev I. G., Moiseenkov A. M. Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 93-96.
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TY - JOUR
DO - 10.1070/MC1993v003n03ABEH000238
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000238
TI - Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid
T2 - Mendeleev Communications
AU - Cheskis, Boris Arnol'dovich
AU - Alekseev, Ivan Gennadievich
AU - Moiseenkov, Aiexsander Makarovich
PY - 1993
DA - 1993/06/30
PB - Mendeleev Communications
SP - 93-96
IS - 3
VL - 3
ER -
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@article{1993_Cheskis,
author = {Boris Arnol'dovich Cheskis and Ivan Gennadievich Alekseev and Aiexsander Makarovich Moiseenkov},
title = {Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000238},
number = {3},
pages = {93--96},
doi = {10.1070/MC1993v003n03ABEH000238}
}
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Cheskis, Boris Arnol'dovich, et al. “Total Synthesis of the Archaebacterial C40-Diol and its Enantiomer Based on(R)-5-Acetoxy-4-methylpentanoic Acid.” Mendeleev Communications, vol. 3, no. 3, Jun. 1993, pp. 93-96. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000238.

Abstract

Optically pure archaebacterial C40-diol 2a and its enantiomer 2b have been synthesized in 17 steps and ca. 2% overall yield using a readily available (R)-5-acetoxy-4-methylpentanoic acid as the single chiral building block.

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