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New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines

Viacheslav A Petrov 1
Viacheslav A Petrov
, 
Darryl D DesMarteau 1
Darryl D DesMarteau
10.1070/MC1993v003n03ABEH000234
Published 1993-06-30
Communication , Volume 3, Issue 3, 87-88
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Petrov V. A., DesMarteau D. D. New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 87-88.
GOST all authors (up to 50) Copy
Petrov V. A., DesMarteau D. D. New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines // Mendeleev Communications. 1993. Vol. 3. No. 3. pp. 87-88.
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TY - JOUR
DO - 10.1070/MC1993v003n03ABEH000234
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000234
TI - New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines
T2 - Mendeleev Communications
AU - Petrov, Viacheslav A
AU - DesMarteau, Darryl D
PY - 1993
DA - 1993/06/30
PB - Mendeleev Communications
SP - 87-88
IS - 3
VL - 3
ER -
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@article{1993_Petrov,
author = {Viacheslav A Petrov and Darryl D DesMarteau},
title = {New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000234},
number = {3},
pages = {87--88},
doi = {10.1070/MC1993v003n03ABEH000234}
}
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Petrov, Viacheslav A., and Darryl D DesMarteau. “New Methods for the Synthesis of Perfluorooxaziridines. Preparation of cis-Perfluoro-2,3-dialkyloxaziridines.” Mendeleev Communications, vol. 3, no. 3, Jun. 1993, pp. 87-88. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n03ABEH000234.

Abstract

In the presence of metal fluorides CF3OOC(O)F oxidizes internal perfluoroazaalkenes forming the coresponding oxaziridines in high yields. Reaction of azaalkenes with CF2(OF)2 in the presence of CsF also gives the oxaziridines in modest yields. Evidence is presented for the intermediacy of the peroxyanion CF3OO– in these reactions, and the synthesis and characterization of the new oxaziridines (Rf, RfN=CFR’f, C2F5 4; n–C4F9, n–C3F7 5; i–C3F7, CF3 6) are described.

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