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Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction

Pavel Stanislavovich Mozhaev 1
Pavel Stanislavovich Mozhaev
, 
Galina Anatol'evna Kichigina 1
Galina Anatol'evna Kichigina
,  , 
Igor Mstislavovich Barkalov 1
Igor Mstislavovich Barkalov
10.1070/MC1993v003n02ABEH000226
Published 1993-04-30
Communication , Volume 3, Issue 2, 64-66
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Mozhaev P. S. et al. Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction // Mendeleev Communications. 1993. Vol. 3. No. 2. pp. 64-66.
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Mozhaev P. S., Kichigina G. A., Kiryukhin D. P., Barkalov I. M. Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction // Mendeleev Communications. 1993. Vol. 3. No. 2. pp. 64-66.
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TY - JOUR
DO - 10.1070/MC1993v003n02ABEH000226
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000226
TI - Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction
T2 - Mendeleev Communications
AU - Mozhaev, Pavel Stanislavovich
AU - Kichigina, Galina Anatol'evna
AU - Kiryukhin, Dmitrii Pavlovich
AU - Barkalov, Igor Mstislavovich
PY - 1993
DA - 1993/04/30
PB - Mendeleev Communications
SP - 64-66
IS - 2
VL - 3
ER -
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@article{1993_Mozhaev,
author = {Pavel Stanislavovich Mozhaev and Galina Anatol'evna Kichigina and Dmitrii Pavlovich Kiryukhin and Igor Mstislavovich Barkalov},
title = {Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000226},
number = {2},
pages = {64--66},
doi = {10.1070/MC1993v003n02ABEH000226}
}
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Mozhaev, Pavel Stanislavovich, et al. “Low-temperature Hydrobromination of Allyl Chloride and Autowave Regime of a Solid State Reaction.” Mendeleev Communications, vol. 3, no. 2, Apr. 1993, pp. 64-66. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000226.

Abstract

Spontaneous hydrobromination of allyl chloride (AC) proceeds in the liquid phase (180–220 K, thermal effect ΔH= 17 kcal mor−1) to give 1-chloro-2-bromopropane; active centres produced by radiolysis at 77 K at the glass transition (87–95 K) initiate a chain addition reaction of HBr to AC to form 1-chloro-3-bromopropane (thermal effect Δ13.2 kcal mor−1). This is the first example of hydrobromination at matrix devitrification; a local brittle fracture of the irradiated sample of AC + HBr gives an autowave of chemical conversion spread over the sample.

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