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Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6 (M = Cu, Ag, Au)

Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
Dmitry Victorovich Muratov 1
Dmitry Victorovich Muratov
Margarita Iosifovna Rybinskaya 1
Margarita Iosifovna Rybinskaya
Urho Turpeinen 2
Urho Turpeinen
Published 1993-04-30
CommunicationVolume 3, Issue 2, 39-40
4
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Kudinov A. R. et al. Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au) // Mendeleev Communications. 1993. Vol. 3. No. 2. pp. 39-40.
GOST all authors (up to 50) Copy
Kudinov A. R., Muratov D. V., Rybinskaya M. I., Turpeinen U. Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au) // Mendeleev Communications. 1993. Vol. 3. No. 2. pp. 39-40.
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TY - JOUR
DO - 10.1070/MC1993v003n02ABEH000210
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000210
TI - Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au)
T2 - Mendeleev Communications
AU - Kudinov, Alexander Rudolfovich
AU - Muratov, Dmitry Victorovich
AU - Rybinskaya, Margarita Iosifovna
AU - Turpeinen, Urho
PY - 1993
DA - 1993/04/30
PB - Mendeleev Communications
SP - 39-40
IS - 2
VL - 3
ER -
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@article{1993_Kudinov,
author = {Alexander Rudolfovich Kudinov and Dmitry Victorovich Muratov and Margarita Iosifovna Rybinskaya and Urho Turpeinen},
title = {Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au)},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000210},
number = {2},
pages = {39--40},
doi = {10.1070/MC1993v003n02ABEH000210}
}
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Kudinov, Alexander Rudolfovich, et al. “Synthesis of Cationic Trigonal-bipyramidal Clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6– (M = Cu, Ag, Au).” Mendeleev Communications, vol. 3, no. 2, Apr. 1993, pp. 39-40. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n02ABEH000210.

Abstract

Novel mixed trigonal-bipyramidal clusters [MRh4(η-C5H5)4(PPh3)(μ3-CO)2]+PF6(M=Cu, Ag, Au) have been prepared by the reaction of Rh4(η-C5H5)(μ,3-CO)2 with [M(PPh3)]+ fragments, generated in situ in CH2CI2 from M(PPh3)Hal.

References

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Heteronuclear Cluster Chemistry of Copper, Silver, and Gold
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Three-membered metallacycle Cp3Rh3(μ-CO)3 as a cluster and benzenoid system in reactions with 12-electron particles PPh3M+ (where M = Cu, Ag, Au) and CpM+ (where M = Fe, Ru)
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Journal of Organometallic Chemistry, 1991
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Use of [(η-C5R5)M]+ fragments (M = Fe, R = H; M = Ru, R = H, Me) for synthesis of cationic cluster. X-Ray structure of [RuRh3(η-C5Me5)(η-C5H5)3(μ3-CO)3]PF6
Kudinov A.R., Muratov D.V., Rybinskaya M.I., petrovskii P.V., Mironov A.V., Timofeeva T.V., Slovokhotov Y.L., Struchkov Y.T.
Journal of Organometallic Chemistry, 1991
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