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Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Valentina Ivanovna Tatarinova 1
Valentina Ivanovna Tatarinova
, 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1070/MC1993v003n01ABEH000207
Published 1993-02-28
Communication , Volume 3, Issue 1, 27-28
3
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Vasil'ev A. A., Tatarinova V. I., Petrosyan V. A. Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 27-28.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Tatarinova V. I., Petrosyan V. A. Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 27-28.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000207
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000207
TI - Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Tatarinova, Valentina Ivanovna
AU - Petrosyan, Vladimir Anushavanovich
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 27-28
IS - 1
VL - 3
ER -
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@article{1993_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Valentina Ivanovna Tatarinova and Vladimir Anushavanovich Petrosyan},
title = {Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000207},
number = {1},
pages = {27--28},
doi = {10.1070/MC1993v003n01ABEH000207}
}
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Vasil'ev, Andrei Alexandrovich, et al. “Cathodic Alkylation of Methyl Phenylacetate and its η6-Tricarbonylchromium Complex.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 27-28. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000207.

Abstract

Electrolysis of methyl phenylacetate or its η6-tricarbonylchromium complex, in MeCN on a Pt cathode in the presence of alkyl bromides, results in mono- and/or di-alkylated products, the yield depending on the nature of the initial reagents. When (methyl phenylacetate)tricarbonylchromium is used decomplexation might also take place as a side reaction

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