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New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
Gulnara Konstantinovna Kadorkina 1
Gulnara Konstantinovna Kadorkina
Anait Genrikovna Mkhitaryan 1
Anait Genrikovna Mkhitaryan
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
Abil E Aliev 1
Abil E Aliev
Published 1993-02-28
CommunicationVolume 3, Issue 1, 21-23
5
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Kostyanovsky R. G. et al. New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 21-23.
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Kostyanovsky R. G., Kadorkina G. K., Mkhitaryan A. G., Chervin I. I., Aliev A. E. New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 21-23.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000204
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000204
TI - New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Kadorkina, Gulnara Konstantinovna
AU - Mkhitaryan, Anait Genrikovna
AU - Chervin, Ivan Ivanovich
AU - Aliev, Abil E
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 21-23
IS - 1
VL - 3
ER -
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@article{1993_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Gulnara Konstantinovna Kadorkina and Anait Genrikovna Mkhitaryan and Ivan Ivanovich Chervin and Abil E Aliev},
title = {New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000204},
number = {1},
pages = {21--23},
doi = {10.1070/MC1993v003n01ABEH000204}
}
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Kostyanovsky, Remir Grigorevich, et al. “New Scope and Limitations in the Knorr–Paal Synthesis of Pyrroles.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 21-23. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000204.

Abstract

Newly-found steric limits for the Knorr–Paal reaction in the case of 2-methyl-1,2-propanediamine and acetonylacetone make it possible for the process to occur with only one amino group, giving aminopyrrole 2, and with aziridines, due to dimerization under the conditions of the reaction, giving 1-((β-aziridinoalkyl)pyrroles 4a,b.

References

1.
Recent Advances in the Chemistry of Pyrrole.
Baltazzi E., Krimen L.I.
Chemical Reviews, 1963
2.
Oligomers of aziridines and N-?-aziridinoethylamides
Kostyanovskii R.G., Leshchinskaya V.P., Alekperov R.K., Kadorkina G.K., Shustova L.L., �l'natanov Y.I., Gromova G.L., Aliev A.�., Chervin I.I.
Russian Chemical Bulletin, 1988
3.
10.1070/MC1993v003n01ABEH000204_bib3
Strack
Hoppe-Seyler's Z. Physiol. Chem., 1929
4.
10.1070/MC1993v003n01ABEH000204_bib4
Kostyanovsky
Dokl. Akad. Nauk SSSR, 1964
5.
10.1070/MC1993v003n01ABEH000204_bib5
Kostyanovsky
Dokl. Akad. Nauk SSSR, 1961
6.
Stickstoffhaltige Steroide, IX. 16α.17α‐Iminoverbindungen der Pregnanreihe