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Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes

Aleksandr Nikolaevich Kasatkin 1
Aleksandr Nikolaevich Kasatkin
, 
Yulia A Prokopenko 1
Yulia A Prokopenko
, 
Arthur M Khabibov 1
Arthur M Khabibov
, 
Genrikh Alexandrovich Tolstikov 2
Genrikh Alexandrovich Tolstikov
10.1070/MC1993v003n01ABEH000201
Published 1993-02-28
Communication , Volume 3, Issue 1, 17-18
3
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Kasatkin A. N. et al. Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 17-18.
GOST all authors (up to 50) Copy
Kasatkin A. N., Prokopenko Y. A., Khabibov A. M., Tolstikov G. A. Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 17-18.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000201
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000201
TI - Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes
T2 - Mendeleev Communications
AU - Kasatkin, Aleksandr Nikolaevich
AU - Prokopenko, Yulia A
AU - Khabibov, Arthur M
AU - Tolstikov, Genrikh Alexandrovich
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 17-18
IS - 1
VL - 3
ER -
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@article{1993_Kasatkin,
author = {Aleksandr Nikolaevich Kasatkin and Yulia A Prokopenko and Arthur M Khabibov and Genrikh Alexandrovich Tolstikov},
title = {Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000201},
number = {1},
pages = {17--18},
doi = {10.1070/MC1993v003n01ABEH000201}
}
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Kasatkin, Aleksandr Nikolaevich, et al. “Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 17-18. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000201.

Abstract

Reactions of organomanganese derivatives of 3-sulfolene and 2-methyl-3-sulfolene with allyl- and propargyl bromides result in high yields of related 2-substituted or 2,5-disubstituted 3-sulfolenes; thermolysis of the cross-coupled products gives 1,3,6-trienes or 1,3-dien-6-ynes.

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