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Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes

Vadim D Romanenko 1
Vadim D Romanenko
, 
Alexander Vladimirovich Ruban 1
Alexander Vladimirovich Ruban
, 
Alexander B Roshenko 1
Alexander B Roshenko
, 
Mark Iosiphovich Povolotskii 1
Mark Iosiphovich Povolotskii
, 
Tatjana V Sarina 1
Tatjana V Sarina
, 
Dietrich Gudat 2
Dietrich Gudat
, 
Edgar Niecke 2
Edgar Niecke
, 
Igor Stepanovich Zaslonko 3
Igor Stepanovich Zaslonko
10.1070/MC1993v003n01ABEH000194
Published 1993-02-28
Communication , Volume 3, Issue 1, 7-8
2
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Romanenko V. D. et al. Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 7-8.
GOST all authors (up to 50) Copy
Romanenko V. D., Ruban A. V., Roshenko A. B., Povolotskii M. I., Sarina T. V., Gudat D., Niecke E., Zaslonko I. S. Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 7-8.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000194
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000194
TI - Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes
T2 - Mendeleev Communications
AU - Romanenko, Vadim D
AU - Ruban, Alexander Vladimirovich
AU - Roshenko, Alexander B
AU - Povolotskii, Mark Iosiphovich
AU - Sarina, Tatjana V
AU - Gudat, Dietrich
AU - Niecke, Edgar
AU - Zaslonko, Igor Stepanovich
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 7-8
IS - 1
VL - 3
ER -
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@article{1993_Romanenko,
author = {Vadim D Romanenko and Alexander Vladimirovich Ruban and Alexander B Roshenko and Mark Iosiphovich Povolotskii and Tatjana V Sarina and Dietrich Gudat and Edgar Niecke and Igor Stepanovich Zaslonko},
title = {Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000194},
number = {1},
pages = {7--8},
doi = {10.1070/MC1993v003n01ABEH000194}
}
MLA
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Romanenko, Vadim D., et al. “Reactions of Iminophosphanes with Chlorotris(triphenylphosphine)rhodium(I): Generation and NMR Identification of the First Iminophosphanerhodium(I) and Iminophosphanerhodium(III) Complexes.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 7-8. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000194.

Abstract

Iminophosphanes [RO-P=NAr] (R = Me, 2-MeC6H4; Ar = 2,4,6-But3C6H2) 1a,b react with RhCIL3 (L = Ph3P) via ligand exchange to give KP-iminophosphane complexes of rhodium(i) [RhCI(MeOP=NAr)2L] 2 and [PhCI(2-MeC6H4OP=NAr)L2] 3. Under analogous conditions, P-halogenoiminophosphanes [X-P=NAr] (X = CI, Br, I) 3a–c undergo a facile oxidative addition of the P—X bond, forming five-coordinate iminophosphanerhodium(iii) complexes of composition [L2CI(X)Rh(<σ-P=BAr)] 5.

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