Home / Publications / Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K

Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K

Evgenii Yakovlevich Misochko ¹

Evgenii Yakovlevich Misochko

Charles A Wight ²

Charles A Wight

Viktor Adol'fovich Benderskii ¹

Viktor Adol'fovich Benderskii

¹ Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

² Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

10.1070/MC1993v003n01ABEH000193

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Published 1993-02-28

Communication , Volume 3, Issue 1, 5-7

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Misochko E. Y., Wight C. A., Benderskii V. A. Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 5-7.

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Misochko E. Y., Wight C. A., Benderskii V. A. Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 5-7.

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TY - JOUR

DO - 10.1070/MC1993v003n01ABEH000193

UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000193

TI - Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K

T2 - Mendeleev Communications

AU - Misochko, Evgenii Yakovlevich

AU - Wight, Charles A

AU - Benderskii, Viktor Adol'fovich

PY - 1993

DA - 1993/02/28

PB - Mendeleev Communications

SP - 5-7

IS - 1

VL - 3

ER -

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@article{1993_Misochko,

author = {Evgenii Yakovlevich Misochko and Charles A Wight and Viktor Adol'fovich Benderskii},

title = {Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K},

journal = {Mendeleev Communications},

year = {1993},

volume = {3},

publisher = {Mendeleev Communications},

month = {Feb},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000193},

number = {1},

pages = {5--7},

doi = {10.1070/MC1993v003n01ABEH000193}

}

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Misochko, Evgenii Yakovlevich, et al. “Solid-state Chain Photochlorination in Recrystallized Mixtures of Ethene and Chlorine at 30 K.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 5-7. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000193.

Abstract

Binary solid films of chlorine with ethene have been deposited in excess argon and subsequently recrystaliized by warmingand evaporation of the argon solvent. This novel recrystallization procedure results in a dramatic increase in the quantumyield and degree of conversion for long stereospecific chain photochlorination with the exclusive formation of thefrans-1,2-dichloroethane.