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Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre

Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
, 
Mikhail Stepanovich Korobov 1
Mikhail Stepanovich Korobov
, 
Leonid Efimovich Nivorozhkin 1
Leonid Efimovich Nivorozhkin
, 
Olga Evgenievna Kompan 1
Olga Evgenievna Kompan
, 
Rita Yakovlevna Olekhnovich 1
Rita Yakovlevna Olekhnovich
, 
Gennadii Sergeevich Borodkin 1
Gennadii Sergeevich Borodkin
, 
Yuri Timofeevich Struchkov 2
Yuri Timofeevich Struchkov
10.1070/MC1993v003n01ABEH000192
Published 1993-02-28
Communication , Volume 3, Issue 1, 2-5
7
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Minkin V. I. et al. Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 2-5.
GOST all authors (up to 50) Copy
Minkin V. I., Korobov M. S., Nivorozhkin L. E., Kompan O. E., Olekhnovich R. Y., Borodkin G. S., Struchkov Y. T. Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 2-5.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000192
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000192
TI - Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre
T2 - Mendeleev Communications
AU - Minkin, Vladimir Isaakovich
AU - Korobov, Mikhail Stepanovich
AU - Nivorozhkin, Leonid Efimovich
AU - Kompan, Olga Evgenievna
AU - Olekhnovich, Rita Yakovlevna
AU - Borodkin, Gennadii Sergeevich
AU - Struchkov, Yuri Timofeevich
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 2-5
IS - 1
VL - 3
ER -
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@article{1993_Minkin,
author = {Vladimir Isaakovich Minkin and Mikhail Stepanovich Korobov and Leonid Efimovich Nivorozhkin and Olga Evgenievna Kompan and Rita Yakovlevna Olekhnovich and Gennadii Sergeevich Borodkin and Yuri Timofeevich Struchkov},
title = {Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000192},
number = {1},
pages = {2--5},
doi = {10.1070/MC1993v003n01ABEH000192}
}
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Minkin, Vladimir Isaakovich, et al. “Low-energy Barrier to Intramolecular Inversion of Tetrahedral Configuration at a Zn” Centre.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 2-5. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000192.

Abstract

The associative inner-nucleophile assisted mechanism of inversion of tetrahedral configuration at the metal centre in bis-chelate Zn” complexes based on alterdentate ligands, A/-alkylimines of 2,5-diformylpyrrole, has been proved by dynamic 1H, 13C, 15N NMR spectroscopic and X-ray crystallographic studies.

References

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Zh. Obshch. Khim., 1991
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Alterdentate ligands
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Edge inversion barrier at a four-coordinate main group IV center
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Solvent stabilization of the edge inversion transition state in tetrahedral molecules
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