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A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture

Elena Vladimirovna Evdokimova 1
Elena Vladimirovna Evdokimova
, 
Valery Vasil'evich Lunin 2
Valery Vasil'evich Lunin
, 
Pavel Vladimirovich Afanasiev 2
Pavel Vladimirovich Afanasiev
, 
Ilya Iosifovich Moiseev 1
Ilya Iosifovich Moiseev
10.1070/MC1993v003n01ABEH000191
Published 1993-02-28
Communication , Volume 3, Issue 1, 1-2
6
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Evdokimova E. V. et al. A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 1-2.
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Evdokimova E. V., Lunin V. V., Afanasiev P. V., Moiseev I. I. A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture // Mendeleev Communications. 1993. Vol. 3. No. 1. pp. 1-2.
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TY - JOUR
DO - 10.1070/MC1993v003n01ABEH000191
UR - https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000191
TI - A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture
T2 - Mendeleev Communications
AU - Evdokimova, Elena Vladimirovna
AU - Lunin, Valery Vasil'evich
AU - Afanasiev, Pavel Vladimirovich
AU - Moiseev, Ilya Iosifovich
PY - 1993
DA - 1993/02/28
PB - Mendeleev Communications
SP - 1-2
IS - 1
VL - 3
ER -
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@article{1993_Evdokimova,
author = {Elena Vladimirovna Evdokimova and Valery Vasil'evich Lunin and Pavel Vladimirovich Afanasiev and Ilya Iosifovich Moiseev},
title = {A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture},
journal = {Mendeleev Communications},
year = {1993},
volume = {3},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000191},
number = {1},
pages = {1--2},
doi = {10.1070/MC1993v003n01ABEH000191}
}
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Evdokimova, Elena Vladimirovna, et al. “A New Method of C02 Activation: Alcohol Homologation with a CO2/H2 Mixture.” Mendeleev Communications, vol. 3, no. 1, Feb. 1993, pp. 1-2. https://mendcomm.colab.ws/publications/10.1070/MC1993v003n01ABEH000191.

Abstract

Homologation of methanol and ethanol has been observed by placing a CO2/H2 (1:1) mixture in contact with a suspension of copper/zirconium polyhydride, Cu3Zr2Hn, in an alcohol–benzene solution; the absence of CO and CH3OH among the reaction products in the ethanol homologation suggests that carbon monoxide and methanol are not involved in the reaction observed.

References

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10.1070/MC1993v003n01ABEH000191_bib2
Lunin
Kinet. Katal., 1987
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Synthesis of Methanol
Chinchen G.C., Denny P.J., Jennings J.R., Spencer M.S., Waugh K.C.
Applied Catalysis, 1988
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Recent progress in solid superacid
Yamaguchi T.
Applied Catalysis, 1990
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10.1070/MC1993v003n01ABEH000191_bib6
Semenenko
Zh. Neorg. Khim., 1980