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Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt

Peter J Stang 1
Peter J Stang
,  , 
Atta M Arif 1
Atta M Arif
10.1070/MC1992v002n04ABEH000184
Published 1992-12-31
Communication , Volume 2, Issue 4, 158-159
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Stang P. J., Zhdankin V. V., Arif A. M. Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 158-159.
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Stang P. J., Zhdankin V. V., Arif A. M. Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 158-159.
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TY - JOUR
DO - 10.1070/MC1992v002n04ABEH000184
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000184
TI - Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt
T2 - Mendeleev Communications
AU - Stang, Peter J
AU - Zhdankin, Viktor Vladimirovich
AU - Arif, Atta M
PY - 1992
DA - 1992/12/31
PB - Mendeleev Communications
SP - 158-159
IS - 4
VL - 2
ER -
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@article{1992_Stang,
author = {Peter J Stang and Viktor Vladimirovich Zhdankin and Atta M Arif},
title = {Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000184},
number = {4},
pages = {158--159},
doi = {10.1070/MC1992v002n04ABEH000184}
}
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Stang, Peter J., et al. “Synthesis and X-Ray Structure Determination of 1,4-Bis[trimethylsilylethynyl(trifluoromethanesulfonyloxy)iodo]benzene, Me3SiC≡Cl+C6H4l+C≡CSiMe3 2CF3SO3−, a Novel Alkynyliodonium Salt.” Mendeleev Communications, vol. 2, no. 4, Dec. 1992, pp. 158-159. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000184.

Abstract

The novel bis(alkynyliodonium) salt, 2, has been prepared by the reaction of p-bis(iodosyl)benzene with trimethylsilyl trifluoromethanesulfonate and bis(trimethylsilyl)acetylene; X-ray structure analysis reveals an unusual basket-like structure for this compound.

References

1.
Alkynyl‐ and Alkenyl(phenyl)iodonium Compounds. New Synthetic Methods (86)
Stang P.J.
Angewandte Chemie International Edition in English, 1992
2.
Alkynyl carboxylate, phosphate, and sulfonate esters
Stang P.J.
Accounts of Chemical Research, 1991
4.
An electrically neutral .sigma.-sulfuranyl radical from the homolysis of a perester with neighboring sulfenyl sulfur: 9-S-3 species
Perkins C.W., Martin J.C., Arduengo A.J., Lau W., Alegria A., Kochi J.K.
Journal of the American Chemical Society, 1980
5.
Preparation and molecular structure determination of dialkynyliodonium salts: (RC.tplbond.C)2I+ -OTf
Stang P.J., Zhdankin V.V., Arif A.M.
Journal of the American Chemical Society, 1991