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A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L)

Vladimir Semenovich Sergienko 1
Vladimir Semenovich Sergienko
, 
Elena Okkasovna Tolkacheva 2
Elena Okkasovna Tolkacheva
, 
Andrei Borisovich Ilyukhin 1
Andrei Borisovich Ilyukhin
, 
Zoya Aleksandrovna Starikova 3
Zoya Aleksandrovna Starikova
, 
Inna Aleksandrovna Krol 2
Inna Aleksandrovna Krol
10.1070/MC1992v002n04ABEH000175
Published 1992-12-31
Communication , Volume 2, Issue 4, 144-146
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Sergienko V. S. et al. A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L) // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 144-146.
GOST all authors (up to 50) Copy
Sergienko V. S., Tolkacheva E. O., Ilyukhin A. B., Starikova Z. A., Krol I. A. A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L) // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 144-146.
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TY - JOUR
DO - 10.1070/MC1992v002n04ABEH000175
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000175
TI - A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L)
T2 - Mendeleev Communications
AU - Sergienko, Vladimir Semenovich
AU - Tolkacheva, Elena Okkasovna
AU - Ilyukhin, Andrei Borisovich
AU - Starikova, Zoya Aleksandrovna
AU - Krol, Inna Aleksandrovna
PY - 1992
DA - 1992/12/31
PB - Mendeleev Communications
SP - 144-146
IS - 4
VL - 2
ER -
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@article{1992_Sergienko,
author = {Vladimir Semenovich Sergienko and Elena Okkasovna Tolkacheva and Andrei Borisovich Ilyukhin and Zoya Aleksandrovna Starikova and Inna Aleksandrovna Krol},
title = {A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L)},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000175},
number = {4},
pages = {144--146},
doi = {10.1070/MC1992v002n04ABEH000175}
}
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Sergienko, Vladimir Semenovich, et al. “A Novel Type of [Mo3O9(L*)]5− Anion in the Structure of an Ammonium−Guanidinium Salt of a MoVI Complex with 1-Hydroxyethylidenediphosphonic Acid (H4L).” Mendeleev Communications, vol. 2, no. 4, Dec. 1992, pp. 144-146. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000175.

Abstract

The synthesis and X-ray analysis of (NH4)2[C(NH2)3]3[MoO3O9(L*)] 2.5H2O have been carried out (L* = L5−); the trinuclear anion has an unusual structure with a different number of terminal oxygen atoms in the ’yl’ groups at the molybdenum atoms (two MoO2 groups and the MoO3 group), where pairs of MoO6 octahedra share a common face or vertex; the structure of the [Mo3O9(L*)]5− anion is similar to that of one half of the [Mo6O17(L2*)]8− hexanuclear anion, in which the central bridging oxygen atom Oc is substituted by a terminal Ot.

References

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Zh. Neorg. Khim., 1992
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Organic derivatives of heteropolymolybdates
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