Home / Publications / Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene

Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene

Sadulla Reimovich Allayarov ¹

Sadulla Reimovich Allayarov

Igor Mstislavovich Barkalov ¹

Igor Mstislavovich Barkalov

Ida Pavlovna Kim ¹

Ida Pavlovna Kim

¹ Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

10.1070/MC1992v002n04ABEH000173

Copy DOI

Published 1992-12-31

Communication , Volume 2, Issue 4, 139-141

View PDF

Cite this

GOST

Cite this

GOST Copy

Allayarov S. R., Barkalov I. M., Kim I. P. Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 139-141.

GOST all authors (up to 50) Copy

Allayarov S. R., Barkalov I. M., Kim I. P. Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 139-141.

RIS

Cite this

RIS Copy

TY - JOUR

DO - 10.1070/MC1992v002n04ABEH000173

UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000173

TI - Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene

T2 - Mendeleev Communications

AU - Allayarov, Sadulla Reimovich

AU - Barkalov, Igor Mstislavovich

AU - Kim, Ida Pavlovna

PY - 1992

DA - 1992/12/31

PB - Mendeleev Communications

SP - 139-141

IS - 4

VL - 2

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{1992_Allayarov,

author = {Sadulla Reimovich Allayarov and Igor Mstislavovich Barkalov and Ida Pavlovna Kim},

title = {Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene},

journal = {Mendeleev Communications},

year = {1992},

volume = {2},

publisher = {Mendeleev Communications},

month = {Dec},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000173},

number = {4},

pages = {139--141},

doi = {10.1070/MC1992v002n04ABEH000173}

}

MLA

Cite this

MLA Copy

Allayarov, Sadulla Reimovich, et al. “Low-temperature Fluorination of Perfluoro-2,4-dimethyl-3-ethylpent-2-ene.” Mendeleev Communications, vol. 2, no. 4, Dec. 1992, pp. 139-141. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000173.

Abstract

Calorimetric and EPR investigations of the low temperature (77–300 K) fluorination of unsaturated perfluorocarbons have shown that, in glassy systems, the formation of molecular complexes of fluorine with a C=C bond is possible during the transition to the supercooled liquid state; chain addition of fluorine to the title compound stops at the first stage, after formation of stable, long-lived radicals.