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Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect

Alexander Borisovich Sorokin 1
Alexander Borisovich Sorokin
, 
Alexander Mikhailovich Khenkin 1
Alexander Mikhailovich Khenkin
, 
Aleksandr Evgen'evich Shilov 2
Aleksandr Evgen'evich Shilov
10.1070/MC1992v002n04ABEH000172
Published 1992-12-31
Communication , Volume 2, Issue 4, 137-139
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Sorokin A. B., Khenkin A. M., Shilov A. E. Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 137-139.
GOST all authors (up to 50) Copy
Sorokin A. B., Khenkin A. M., Shilov A. E. Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 137-139.
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TY - JOUR
DO - 10.1070/MC1992v002n04ABEH000172
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000172
TI - Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect
T2 - Mendeleev Communications
AU - Sorokin, Alexander Borisovich
AU - Khenkin, Alexander Mikhailovich
AU - Shilov, Aleksandr Evgen'evich
PY - 1992
DA - 1992/12/31
PB - Mendeleev Communications
SP - 137-139
IS - 4
VL - 2
ER -
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@article{1992_Sorokin,
author = {Alexander Borisovich Sorokin and Alexander Mikhailovich Khenkin and Aleksandr Evgen'evich Shilov},
title = {Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000172},
number = {4},
pages = {137--139},
doi = {10.1070/MC1992v002n04ABEH000172}
}
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Sorokin, Alexander Borisovich, et al. “Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect.” Mendeleev Communications, vol. 2, no. 4, Dec. 1992, pp. 137-139. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000172.

Abstract

Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH− action are discussed

References

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