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Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds

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Dzhemilev U. M., Ibragimov A. G., Zolotarev A. P. Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 135-136.
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Dzhemilev U. M., Ibragimov A. G., Zolotarev A. P. Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds // Mendeleev Communications. 1992. Vol. 2. No. 4. pp. 135-136.
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TY - JOUR
DO - 10.1070/MC1992v002n04ABEH000170
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000170
TI - Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds
T2 - Mendeleev Communications
AU - Dzhemilev, Usein Memetovich
AU - Ibragimov, Askhat Gabdrakhmanovich
AU - Zolotarev, Aleksei Petrovich
PY - 1992
DA - 1992/12/31
PB - Mendeleev Communications
SP - 135-136
IS - 4
VL - 2
ER -
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@article{1992_Dzhemilev,
author = {Usein Memetovich Dzhemilev and Askhat Gabdrakhmanovich Ibragimov and Aleksei Petrovich Zolotarev},
title = {Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000170},
number = {4},
pages = {135--136},
doi = {10.1070/MC1992v002n04ABEH000170}
}
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Dzhemilev, Usein Memetovich, et al. “Synthesis of 1-Ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes. A Novel Class of Five-membered Organoaluminium Compounds.” Mendeleev Communications, vol. 2, no. 4, Dec. 1992, pp. 135-136. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n04ABEH000170.

Abstract

A method has been developed to synthesize a novel class of organoaluminium compounds, 1-ethyl-cis-2,3-dialkyl(aryl)aluminacyclopent-2-enes, starting from disubstituted acetylenes and AIEt3 assisted by catalytic amounts (3–5 mol %) of Cp2ZrCl2 (Cp = η5-C5H5).

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