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The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran)

Dmitrii Mikhailovich Roitershtein 1
Dmitrii Mikhailovich Roitershtein
, 
Arkadii Moiseevich Ellern 2
Arkadii Moiseevich Ellern
, 
Mikhail Yuvenal'evich Antipin 3
Mikhail Yuvenal'evich Antipin
, 
Lyudmila Fedorovna Rybakova 1
Lyudmila Fedorovna Rybakova
, 
Yuri Timofeevich Struchkov 3
Yuri Timofeevich Struchkov
, 
Èduard Sergeevich Petrov 1
Èduard Sergeevich Petrov
10.1070/MC1992v002n03ABEH000165
Published 1992-09-30
Communication , Volume 2, Issue 3, 118-120
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Roitershtein D. M. et al. The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran) // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 118-120.
GOST all authors (up to 50) Copy
Roitershtein D. M., Ellern A. M., Antipin M. Y., Rybakova L. F., Struchkov Y. T., Petrov È. S. The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran) // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 118-120.
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TY - JOUR
DO - 10.1070/MC1992v002n03ABEH000165
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000165
TI - The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran)
T2 - Mendeleev Communications
AU - Roitershtein, Dmitrii Mikhailovich
AU - Ellern, Arkadii Moiseevich
AU - Antipin, Mikhail Yuvenal'evich
AU - Rybakova, Lyudmila Fedorovna
AU - Struchkov, Yuri Timofeevich
AU - Petrov, Èduard Sergeevich
PY - 1992
DA - 1992/09/30
PB - Mendeleev Communications
SP - 118-120
IS - 3
VL - 2
ER -
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@article{1992_Roitershtein,
author = {Dmitrii Mikhailovich Roitershtein and Arkadii Moiseevich Ellern and Mikhail Yuvenal'evich Antipin and Lyudmila Fedorovna Rybakova and Yuri Timofeevich Struchkov and Èduard Sergeevich Petrov},
title = {The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran)},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000165},
number = {3},
pages = {118--120},
doi = {10.1070/MC1992v002n03ABEH000165}
}
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Roitershtein, Dmitrii Mikhailovich, et al. “The First Structurally Characterized Organolanthanoid Compound with an Anthracene Dianion Ligand. Synthesis and Structure (at 143 K) of η5-(C5H5)LU(C14H10 2−) 2thf (thf = tetrahydrofuran).” Mendeleev Communications, vol. 2, no. 3, Sep. 1992, pp. 118-120. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000165.

Abstract

The interaction of -η5-(C5H5)LuCI2 with Na+2(C14H10 2−) or Na+(C14H1O 2−) has led to the formation of η5-(C5H5)LU(C14H10 2−) -2thf (thf = tetrahydrofuran), containing anthracene dianion as a ligand and the structure of the new complex has been established by a low-temperature X-ray diffraction study at 143 K.

References

1.
10.1070/MC1992v002n03ABEH000165_bib1
Szwarc
Carbanions. Living Polymer and Electron Transfer Processes, 1968
3.
10.1070/MC1992v002n03ABEH000165_bib3
Roitershtein
Dokl. Akad. Nauk SSSR, 1990
5.
An empirical method for correcting diffractometer data for absorption effects
Walker N., Stuart D.
Acta Crystallographica Section A Foundations of Crystallography, 1983
6.
The formation and x-ray crystal structure of (η5-C5H5)2LuCl · OC4H8
Ni C., Zhang Z., Deng D., Qian C.
Journal of Organometallic Chemistry, 1986
7.
10.1070/MC1992v002n03ABEH000165_bib7
Zefirov
Zh. Strukt. Khim., 1974
8.
10.1070/MC1992v002n03ABEH000165_bib8
Ni
Inorg. Chim. Acta, 1985
9.
Organo-magnesium reagents: the crystal structures of [Mg(anthracene)(THF)3] and [Mg(triphenylmethyl)Br(OEt2)2]
Engelhardt L.M., Harvey S., Raston C.L., White A.H.
Journal of Organometallic Chemistry, 1988