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6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation

Vyacheslav Gennad'evich Shubin 1
Vyacheslav Gennad'evich Shubin
, 
Makhmut Minakhmetovich Shakirov 1
Makhmut Minakhmetovich Shakirov
, 
Sandor M Nagy 1
Sandor M Nagy
, 
Stanislav Aleksandrovich Osadchii 1
Stanislav Aleksandrovich Osadchii
10.1070/MC1992v002n03ABEH000159
Published 1992-09-30
Communication , Volume 2, Issue 3, 110-111
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Shubin V. G. et al. 6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 110-111.
GOST all authors (up to 50) Copy
Shubin V. G., Shakirov M. M., Nagy S. M., Osadchii S. A. 6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 110-111.
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TY - JOUR
DO - 10.1070/MC1992v002n03ABEH000159
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000159
TI - 6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation
T2 - Mendeleev Communications
AU - Shubin, Vyacheslav Gennad'evich
AU - Shakirov, Makhmut Minakhmetovich
AU - Nagy, Sandor M
AU - Osadchii, Stanislav Aleksandrovich
PY - 1992
DA - 1992/09/30
PB - Mendeleev Communications
SP - 110-111
IS - 3
VL - 2
ER -
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@article{1992_Shubin,
author = {Vyacheslav Gennad'evich Shubin and Makhmut Minakhmetovich Shakirov and Sandor M Nagy and Stanislav Aleksandrovich Osadchii},
title = {6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000159},
number = {3},
pages = {110--111},
doi = {10.1070/MC1992v002n03ABEH000159}
}
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Shubin, Vyacheslav Gennad'evich, et al. “6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl Cation.” Mendeleev Communications, vol. 2, no. 3, Sep. 1992, pp. 110-111. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000159.

Abstract

The 6-lsopropylidene-1,2,3,4,5-pentamethylbicyclo[3.1.0]hex-3-en-2-yl cation, formed as a result of the rearrangement of4-(4′-methylpent-2′-yn-4′-yl)-1,2,3,4-tetramethylcyclobutenyl cation, shows no tendency to undergo a walk rearrangement but is capable of easy ring-opening to form the corresponding benzyl ion, 2-(2,3,4,5,6-pentamethylphenyl)-2-propyl cation.

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