Home / Publications / A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali

A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali

Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
, 
Anton Mikhailovich Gal'minas 1
Anton Mikhailovich Gal'minas
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC1992v002n03ABEH000156
Published 1992-09-30
Communication , Volume 2, Issue 3, 105-106
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Egorov M. P., Gal'minas A. M., Nefedov O. M. A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 105-106.
GOST all authors (up to 50) Copy
Egorov M. P., Gal'minas A. M., Nefedov O. M. A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 105-106.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1992v002n03ABEH000156
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000156
TI - A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali
T2 - Mendeleev Communications
AU - Egorov, Mikhail Petrovich
AU - Gal'minas, Anton Mikhailovich
AU - Nefedov, Oleg Matveevich
PY - 1992
DA - 1992/09/30
PB - Mendeleev Communications
SP - 105-106
IS - 3
VL - 2
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1992_Egorov,
author = {Mikhail Petrovich Egorov and Anton Mikhailovich Gal'minas and Oleg Matveevich Nefedov},
title = {A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000156},
number = {3},
pages = {105--106},
doi = {10.1070/MC1992v002n03ABEH000156}
}
MLA
Cite this
MLA Copy
Egorov, Mikhail Petrovich, et al. “A New Method of Generating Anionic σ-Complexes by the Reaction of 7-Silanorbornadiene with Alkali.” Mendeleev Communications, vol. 2, no. 3, Sep. 1992, pp. 105-106. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000156.

Abstract

The reaction of 7-silanorbornadiene 1 with dry KOH results in the formation of the long-lived anionic σ-complex 2.

References

1.
Aromatic Nucleophilic Substitution Reactions.
Bunnett J.F., Zahler R.E.
Chemical Reviews, 1951
2.
Anionic sigma complexes
Strauss M.J.
Chemical Reviews, 1970
3.
Some Aspects of Anionic σ Complexes
Artamkina G.A., Egorov M.P., Beletskaya I.P.
Chemical Reviews, 1982
5.
Aromatic Nucleophilic Substitution. VII. Electronic Structure of 1,1-Disubstituted 2,4-Dinitronaphthalene Meisenheimer Complexes
Sekiguchi S., Tsutsumi K., Shizuka H., Matsui K., Itagaki T.
Bulletin of the Chemical Society of Japan, 1976
7.
10.1070/MC1992v002n03ABEH000156_bib7
Eaborn
Intra-Sci. Chem. Rep., 1973
11.
Gas-phase reactions of cyclic silanes
Sullivan S.A., DePuy C.H., Damrauer R.
Journal of the American Chemical Society, 1981
12.
Relative gas-phase acidities of the alkanes
DePuy C.H., Bierbaum V.M., Damrauer R.
Journal of the American Chemical Society, 1984