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An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime

Andrei Mikhailovich Chibiryaev 1
Andrei Mikhailovich Chibiryaev
, 
Irina Yur'evna Bagryanskaya 1
Irina Yur'evna Bagryanskaya
, 
Yuriy Vasil'evich Gatilov 1
Yuriy Vasil'evich Gatilov
, 
Alexey Vasil'evich Tkachev 1
Alexey Vasil'evich Tkachev
10.1070/MC1992v002n03ABEH000142
Published 1992-09-30
Communication , Volume 2, Issue 3, 82-83
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Chibiryaev A. M. et al. An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 82-83.
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Chibiryaev A. M., Bagryanskaya I. Y., Gatilov Y. V., Tkachev A. V. An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime // Mendeleev Communications. 1992. Vol. 2. No. 3. pp. 82-83.
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TY - JOUR
DO - 10.1070/MC1992v002n03ABEH000142
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000142
TI - An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime
T2 - Mendeleev Communications
AU - Chibiryaev, Andrei Mikhailovich
AU - Bagryanskaya, Irina Yur'evna
AU - Gatilov, Yuriy Vasil'evich
AU - Tkachev, Alexey Vasil'evich
PY - 1992
DA - 1992/09/30
PB - Mendeleev Communications
SP - 82-83
IS - 3
VL - 2
ER -
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@article{1992_Chibiryaev,
author = {Andrei Mikhailovich Chibiryaev and Irina Yur'evna Bagryanskaya and Yuriy Vasil'evich Gatilov and Alexey Vasil'evich Tkachev},
title = {An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000142},
number = {3},
pages = {82--83},
doi = {10.1070/MC1992v002n03ABEH000142}
}
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Chibiryaev, Andrei Mikhailovich, et al. “An Unusual Dimerization in the Nitrosation Reaction of a Caryophyllene-type α,β-Unsaturated Oxime.” Mendeleev Communications, vol. 2, no. 3, Sep. 1992, pp. 82-83. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n03ABEH000142.

Abstract

The treatment of two isomeric α,β-unsaturated oximes derived from the sesquiterpene hydrocarbon caryophyllene with nitrous acid, generated in situ from sodium nitrite and acetic acid, results in the formation of an unusual dimeric product whose structure was determined by X-ray crystallographic analysis.

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