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Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide

Alois Haas 1
Alois Haas
, 
Yurii Lvovich Yagupolskii 2
Yurii Lvovich Yagupolskii
, 
Christiane Klare 1
Christiane Klare
2 Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
10.1070/MC1992v002n02ABEH000139
Published 1992-06-30
Communication , Volume 2, Issue 2, 70-70
5
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Haas A., Yagupolskii Y. L., Klare C. Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 70-70.
GOST all authors (up to 50) Copy
Haas A., Yagupolskii Y. L., Klare C. Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 70-70.
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TY - JOUR
DO - 10.1070/MC1992v002n02ABEH000139
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000139
TI - Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide
T2 - Mendeleev Communications
AU - Haas, Alois
AU - Yagupolskii, Yurii Lvovich
AU - Klare, Christiane
PY - 1992
DA - 1992/06/30
PB - Mendeleev Communications
SP - 70-70
IS - 2
VL - 2
ER -
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@article{1992_Haas,
author = {Alois Haas and Yurii Lvovich Yagupolskii and Christiane Klare},
title = {Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000139},
number = {2},
pages = {70--70},
doi = {10.1070/MC1992v002n02ABEH000139}
}
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Haas, Alois, et al. “Preparation and Pyrolysis of Phenyldiazonium Bis(trifluoromethylsulfonyl)amide.” Mendeleev Communications, vol. 2, no. 2, Jun. 1992, pp. 70-70. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000139.

Abstract

The stable phenyldiazonium bis(trifluoromethylsulfonyl)amide has been made by reacting PhN2+Cl− with HN(SO2CF3)2 in water, which on heating led to N-(trifluoromethylsulfonyl)phenoxytrifluoromethylsulfoximine (62%) and PhN(SO2CF3)2 (5%) as the products of O- and N-attack by the phenyl cation.

References

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Aryl esters of tris(fluorosulphonyl)methane aci form
Yagupolskii Y.L., Savina T.I., Yufit D.S., Struchkov Y.T.
Tetrahedron Letters, 1983
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10.1070/MC1992v002n02ABEH000139_bib2
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Zh. Org. Khim., 1985
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10.1070/MC1992v002n02ABEH000139_bib3
Yagupolskii
Zh. Org. Khim., 1990
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Yagupolskii
Zh. Org. Khim., 1991
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10.1070/MC1992v002n02ABEH000139_bib5
Haas
Chimia, 1986
7.
L. M. Yagupolskii, Aromaticheskie soedineniya sftorsoderzhashchimi zamestitelyami (Aromatic Compounds with Fluorocontaining Substituents), Naukova Dumka, Kiev, 1988, p. 260 (in Russian).