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Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes

Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
, 
Alexei Alekseevich Filchikov 1
Alexei Alekseevich Filchikov
, 
Margarita Iosifovna Rybinskaya 1
Margarita Iosifovna Rybinskaya
10.1070/MC1992v002n02ABEH000136
Published 1992-06-30
Communication , Volume 2, Issue 2, 64-65
3
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Kudinov A. R., Filchikov A. A., Rybinskaya M. I. Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 64-65.
GOST all authors (up to 50) Copy
Kudinov A. R., Filchikov A. A., Rybinskaya M. I. Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 64-65.
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TY - JOUR
DO - 10.1070/MC1992v002n02ABEH000136
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000136
TI - Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes
T2 - Mendeleev Communications
AU - Kudinov, Alexander Rudolfovich
AU - Filchikov, Alexei Alekseevich
AU - Rybinskaya, Margarita Iosifovna
PY - 1992
DA - 1992/06/30
PB - Mendeleev Communications
SP - 64-65
IS - 2
VL - 2
ER -
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@article{1992_Kudinov,
author = {Alexander Rudolfovich Kudinov and Alexei Alekseevich Filchikov and Margarita Iosifovna Rybinskaya},
title = {Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000136},
number = {2},
pages = {64--65},
doi = {10.1070/MC1992v002n02ABEH000136}
}
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Kudinov, Alexander Rudolfovich, et al. “Deprotonation and Subsequent Functionalization of Methyl Groups in Cationic Ruthenium Triple-decker Complexes.” Mendeleev Communications, vol. 2, no. 2, Jun. 1992, pp. 64-65. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000136.

Abstract

The cationic complex [(η-C5Me5)Ru(μ,η-C5Me5)Ru(η-C5Me5)]+ undergoes deprotonation of the terminal ring methyl groups on treatment with BunLi-Bu’OK at – 78°C in tetrahydrofuran; subsequent treatment with EX reagents gives rise to functionalized complexes [(η-C5Me5)Ru(μ,η-C5Me5)Ru(η-C5Me4CH2E)]+ (E = Me, Me3Si, EtS).

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