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Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase

Alexander Mikhailovich Khenkin 1
Alexander Mikhailovich Khenkin
, 
Marina L Stepanova 1
Marina L Stepanova
10.1070/MC1992v002n02ABEH000131
Published 1992-06-30
Communication , Volume 2, Issue 2, 57-58
3
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Khenkin A. M., Stepanova M. L. Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 57-58.
GOST all authors (up to 50) Copy
Khenkin A. M., Stepanova M. L. Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 57-58.
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TY - JOUR
DO - 10.1070/MC1992v002n02ABEH000131
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000131
TI - Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase
T2 - Mendeleev Communications
AU - Khenkin, Alexander Mikhailovich
AU - Stepanova, Marina L
PY - 1992
DA - 1992/06/30
PB - Mendeleev Communications
SP - 57-58
IS - 2
VL - 2
ER -
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@article{1992_Khenkin,
author = {Alexander Mikhailovich Khenkin and Marina L Stepanova},
title = {Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000131},
number = {2},
pages = {57--58},
doi = {10.1070/MC1992v002n02ABEH000131}
}
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Khenkin, Alexander Mikhailovich, and Marina L Stepanova. “Activation of Dioxygen by Catecholate Binuclear Iron Complexes for Alkane Hydroxylation. A Chemical Model for Methane Monooxygenase.” Mendeleev Communications, vol. 2, no. 2, Jun. 1992, pp. 57-58. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000131.

Abstract

A new model is proposed for methane monooxygenase activation of O2 on binuclear catecholate iron complexes as catalytic centres in the presence of hydrazobenzene as a reducing agent, to oxidize alkanes (including methane).

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