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The First Synthesis of Norbornadiene Tetramers

, 
Ravil Ismagilovich Khusnutdinov 1
Ravil Ismagilovich Khusnutdinov
, 
Damir Kh Galeev 2
Damir Kh Galeev
, 
Alexsander Ivanovich Malikov 2
Alexsander Ivanovich Malikov
, 
Oleg Matveevich Nefedov 3
Oleg Matveevich Nefedov
, 
10.1070/MC1992v002n02ABEH000130
Published 1992-06-30
Communication , Volume 2, Issue 2, 56-57
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Dzhemilev U. M. et al. The First Synthesis of Norbornadiene Tetramers // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 56-57.
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Dzhemilev U. M., Khusnutdinov R. I., Galeev D. Kh., Malikov A. I., Nefedov O. M., Tomilov Y. V. The First Synthesis of Norbornadiene Tetramers // Mendeleev Communications. 1992. Vol. 2. No. 2. pp. 56-57.
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TY - JOUR
DO - 10.1070/MC1992v002n02ABEH000130
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000130
TI - The First Synthesis of Norbornadiene Tetramers
T2 - Mendeleev Communications
AU - Dzhemilev, Usein Memetovich
AU - Khusnutdinov, Ravil Ismagilovich
AU - Galeev, Damir Kh
AU - Malikov, Alexsander Ivanovich
AU - Nefedov, Oleg Matveevich
AU - Tomilov, Yury Vasil'evich
PY - 1992
DA - 1992/06/30
PB - Mendeleev Communications
SP - 56-57
IS - 2
VL - 2
ER -
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@article{1992_Dzhemilev,
author = {Usein Memetovich Dzhemilev and Ravil Ismagilovich Khusnutdinov and Damir Kh Galeev and Alexsander Ivanovich Malikov and Oleg Matveevich Nefedov and Yury Vasil'evich Tomilov},
title = {The First Synthesis of Norbornadiene Tetramers},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000130},
number = {2},
pages = {56--57},
doi = {10.1070/MC1992v002n02ABEH000130}
}
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Dzhemilev, Usein Memetovich, et al. “The First Synthesis of Norbornadiene Tetramers.” Mendeleev Communications, vol. 2, no. 2, Jun. 1992, pp. 56-57. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n02ABEH000130.
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Abstract

Norbornadiene tetramers exo-trans-exo-trans-exo-endo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020,24]octacos-8-ene 2 and exo-trans-exo-trans-exo-exo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020.24]octanos-8-ene 3 have been synthesized in 32% total yield, via Pd complex catalysed cyclodimerization of a known norbornadiene trimer exo-trans-exo-trans-exo-octacyclo[8.8.1.14,7.113,16.02,9.03,8.011,18.012,17]henicosa-5,14-diene 1 with quadricyclane.

References

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Khusnutdinov
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QUADRICYCLANE
Organic Syntheses, 1971
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10.1070/MC1992v002n02ABEH000130_bib5
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