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Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen

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Alla Nikolaevna Druzhinina 1
Alla Nikolaevna Druzhinina
10.1070/MC1992v002n01ABEH000116
Published 1992-03-31
Communication , Volume 2, Issue 1, 36-37
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Shul'pin G. B., Druzhinina A. N. Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 36-37.
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Shul'pin G. B., Druzhinina A. N. Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 36-37.
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TY - JOUR
DO - 10.1070/MC1992v002n01ABEH000116
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000116
TI - Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen
T2 - Mendeleev Communications
AU - Shul'pin, Georgiy Borisovich
AU - Druzhinina, Alla Nikolaevna
PY - 1992
DA - 1992/03/31
PB - Mendeleev Communications
SP - 36-37
IS - 1
VL - 2
ER -
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@article{1992_Shul'pin,
author = {Georgiy Borisovich Shul'pin and Alla Nikolaevna Druzhinina},
title = {Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000116},
number = {1},
pages = {36--37},
doi = {10.1070/MC1992v002n01ABEH000116}
}
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Shul'pin, Georgiy Borisovich, and Alla Nikolaevna Druzhinina. “Iron(III) Chloride Catalysed Photooxygenation of Alcohol Solutions of Alkanes by Atmospheric Oxygen.” Mendeleev Communications, vol. 2, no. 1, Mar. 1992, pp. 36-37. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000116.

Abstract

Alkanes (cyclohexane, pentane, hexane, heptane, 3-methylhexane) have been oxidised to the corresponding alcohols, together with minor amounts of ketones (aldehydes) by irradiation of solutions of the alkanes in aliphatic alcohols in air in the presence of catalytic amounts of FeCI3: unusual selectivity in the reaction is revealed.

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