Home / Publications / Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes

Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes

Mikhail Moiseevich Levitskii 1
Mikhail Moiseevich Levitskii
, 
Aleksandr Yu D'yakonov 2
Aleksandr Yu D'yakonov
, 
Anatolii Leonidovich Buchachenko 2
Anatolii Leonidovich Buchachenko
10.1070/MC1992v002n01ABEH000113
Published 1992-03-31
Communication , Volume 2, Issue 1, 32-33
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Levitskii M. M., D'yakonov A. Yu., Buchachenko A. L. Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 32-33.
GOST all authors (up to 50) Copy
Levitskii M. M., D'yakonov A. Yu., Buchachenko A. L. Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 32-33.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1992v002n01ABEH000113
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000113
TI - Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes
T2 - Mendeleev Communications
AU - Levitskii, Mikhail Moiseevich
AU - D'yakonov, Aleksandr Yu
AU - Buchachenko, Anatolii Leonidovich
PY - 1992
DA - 1992/03/31
PB - Mendeleev Communications
SP - 32-33
IS - 1
VL - 2
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1992_Levitskii,
author = {Mikhail Moiseevich Levitskii and Aleksandr Yu D'yakonov and Anatolii Leonidovich Buchachenko},
title = {Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000113},
number = {1},
pages = {32--33},
doi = {10.1070/MC1992v002n01ABEH000113}
}
MLA
Cite this
MLA Copy
Levitskii, Mikhail Moiseevich, et al. “Unusual Magnetic Behaviour of Polyferro(phenyl)siloxanes.” Mendeleev Communications, vol. 2, no. 1, Mar. 1992, pp. 32-33. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000113.

Abstract

Polyferro(phenyl)siloxanes are paramagnetic when the iron content is low, e.g. at a ratio Fe:Si<2.0, but when Fe:Si>2.0 the effective magnetic moment of the FeIII atom increases with increase of the Fe:Si ratio and it also increases as the temperature decreases; this unusual magnetic behaviour may be explained in terms of spin frustration in polynuclear oxo-ferric polymer clusters.

References

1.
10.1070/MC1992v002n01ABEH000113_bib1
Buchachenko
Mol. Cryst. Liq. Cryst., 1989
2.
10.1070/MC1992v002n01ABEH000113_bib2
Zhdanov
Mol. Cryst. Liq. Cryst., 1989
3.
Spin frustration: a hexanuclear ferric complex with a S = 5 ground state
McCusker J.K., Christmas C.A., Hagen P.M., Chadha R.K., Harvey D.F., Hendrickson D.N.
Journal of the American Chemical Society, 1991
4.
Molecular spin frustration in the [Fe4O2]8+ core: synthesis, structure, and magnetochemistry of tetranuclear iron-oxo complex [Fe4O2(O2CR)7(bpy)2](C1O4) (R = Me, Ph)
McCusker J.K., Vincent J.B., Schmitt E.A., Mino M.L., Shin K., Coggin D.K., Hagen P.M., Huffman J.C., Christou G., Hendrickson D.N.
Journal of the American Chemical Society, 1991