Home / Publications / Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals

Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals

Rakhim Rashidovich Rakhimov 1
Rakhim Rashidovich Rakhimov
, 
Aleksandr I Semikopny 2
Aleksandr I Semikopny
, 
Yakov Sergeevich Lebedev 3
Yakov Sergeevich Lebedev
10.1070/MC1992v002n01ABEH000093
Published 1992-03-31
Communication , Volume 2, Issue 1, 2-4
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Rakhimov R. R., Semikopny A. I., Lebedev Y. S. Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 2-4.
GOST all authors (up to 50) Copy
Rakhimov R. R., Semikopny A. I., Lebedev Y. S. Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 2-4.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1992v002n01ABEH000093
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000093
TI - Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals
T2 - Mendeleev Communications
AU - Rakhimov, Rakhim Rashidovich
AU - Semikopny, Aleksandr I
AU - Lebedev, Yakov Sergeevich
PY - 1992
DA - 1992/03/31
PB - Mendeleev Communications
SP - 2-4
IS - 1
VL - 2
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1992_Rakhimov,
author = {Rakhim Rashidovich Rakhimov and Aleksandr I Semikopny and Yakov Sergeevich Lebedev},
title = {Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000093},
number = {1},
pages = {2--4},
doi = {10.1070/MC1992v002n01ABEH000093}
}
MLA
Cite this
MLA Copy
Rakhimov, Rakhim Rashidovich, et al. “Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals.” Mendeleev Communications, vol. 2, no. 1, Mar. 1992, pp. 2-4. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000093.

Abstract

The spin exchange dynamics and the rotational mobility of rigid-frame nitroxide biradicals have been studied by EPR; despite the intramolecular character of the exchange, its rate correlates with molecular mobility, being damped in viscous media, thus proving that even the simplest intramolecular reactions are controlled by molecular dynamics.

References

2.
10.1070/MC1992v002n01ABEH000093_bib2
Lebedev
Sov. Set. Rev., Sect. B., 1987
3.
10.1070/MC1992v002n01ABEH000093_bib3
Rakhimov
Dokl. Akad. Nauk SSSR, 1988
4.
10.1070/MC1992v002n01ABEH000093_bib4
Rakhimov
Zh. Fiz. Khim., 1990
5.
10.1070/MC1992v002n01ABEH000093_bib5
Parmon
Stabilnie biradicaly (Stable biradicals), 1980
6.
10.1070/MC1992v002n01ABEH000093_bib6
Shapiro
Izv. Akad. Nauk SSSR, Ser. Khim., 1973
7.
10.1070/MC1992v002n01ABEH000093_bib7
Rakhimov
Dokl. Akad. Nauk SSSR, 1988
8.
10.1070/MC1992v002n01ABEH000093_bib8
Rakhimov
Khim. Fiz., 1989