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The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions

Evgenii Timofeevich Denisov 1
Evgenii Timofeevich Denisov
10.1070/MC1992v002n01ABEH000092
Published 1992-03-31
Communication , Volume 2, Issue 1, 1-2
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Denisov E. T. The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 1-2.
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Denisov E. T. The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions // Mendeleev Communications. 1992. Vol. 2. No. 1. pp. 1-2.
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TY - JOUR
DO - 10.1070/MC1992v002n01ABEH000092
UR - https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000092
TI - The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions
T2 - Mendeleev Communications
AU - Denisov, Evgenii Timofeevich
PY - 1992
DA - 1992/03/31
PB - Mendeleev Communications
SP - 1-2
IS - 1
VL - 2
ER -
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@article{1992_Denisov,
author = {Evgenii Timofeevich Denisov},
title = {The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions},
journal = {Mendeleev Communications},
year = {1992},
volume = {2},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000092},
number = {1},
pages = {1--2},
doi = {10.1070/MC1992v002n01ABEH000092}
}
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Denisov, Evgenii Timofeevich. “The Parabolic Transition State Model and Resultant Nonlinear Correlations for the Kinetics of Free Radical Reactions.” Mendeleev Communications, vol. 2, no. 1, Mar. 1992, pp. 1-2. https://mendcomm.colab.ws/publications/10.1070/MC1992v002n01ABEH000092.

Abstract

The transition state of a radical reaction may be treated as the point of intersection of two undisturbed potential curves, each of which characterises the energy of vibration of the atom attacked in either the initial molecule or that formed; a series of nonlinear equations of correlation has been derived for the dependence of the activation energy of a free radical abstraction reaction on the heat of reaction, the energy of triplet repulsion and the electronegativities of the atoms.

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