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Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines

Sokhrab Akhmedovich Ismailov 1
Sokhrab Akhmedovich Ismailov
Mansur Sagar'yarovich Miftakhov 1
Mansur Sagar'yarovich Miftakhov
Genrikh Alexandrovich Tolstikov 2
Genrikh Alexandrovich Tolstikov
Published 1991-12-31
CommunicationVolume 1, Issue 4, 149-151
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Ismailov S. A., Miftakhov M. S., Tolstikov G. A. Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 149-151.
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Ismailov S. A., Miftakhov M. S., Tolstikov G. A. Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 149-151.
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TY - JOUR
DO - 10.1070/MC1991v001n04ABEH000091
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000091
TI - Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines
T2 - Mendeleev Communications
AU - Ismailov, Sokhrab Akhmedovich
AU - Miftakhov, Mansur Sagar'yarovich
AU - Tolstikov, Genrikh Alexandrovich
PY - 1991
DA - 1991/12/31
PB - Mendeleev Communications
SP - 149-151
IS - 4
VL - 1
ER -
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@article{1991_Ismailov,
author = {Sokhrab Akhmedovich Ismailov and Mansur Sagar'yarovich Miftakhov and Genrikh Alexandrovich Tolstikov},
title = {Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000091},
number = {4},
pages = {149--151},
doi = {10.1070/MC1991v001n04ABEH000091}
}
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Ismailov, Sokhrab Akhmedovich, et al. “Unusual Reactions of 2,3,5-Trichloro-4,4-dimethoxy-5-allylcyclopent-2-en-1-one with Amines.” Mendeleev Communications, vol. 1, no. 4, Dec. 1991, pp. 149-151. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000091.

Abstract

The transformation of enaminochlorovinyl ketone 2 via the diketone 3 into a mixture of keto–enol tautomers 4 and 5, synthons for 13-azaprostanoids, is described; reactions of compound 1 with amine derivatives of different types leading to abnormal products have also been studied.

References

1.
G. A. Tolstikov, S. A. Ismailov, Z. B. Badretdinova, G. G. Balezina and M. S. Miftakhov, Zh. Org. Khim., 1991 in the press.
2.
10.1070/MC1991v001n04ABEH000091_bib2
Ismailov
Zh. Org. Khim., 1989
3.
Preparation of 9-hydroxy-14-azaprostanoic acids
Cho B., Chadha V.K., Le Breton G.C., Venton D.L.
Journal of Organic Chemistry, 1986
4.
10.1070/MC1991v001n04ABEH000091_bib4
Ziegler
Angew. Chem., 1955