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1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond

Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
, 
Maria Borisovna Ezhova 1
Maria Borisovna Ezhova
, 
Stanislav Petrovich Kolesnikov 1
Stanislav Petrovich Kolesnikov
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
, 
Mark Borisovich Taraban 2
Mark Borisovich Taraban
, 
Alexander Ivanovich Kruppa 2
Alexander Ivanovich Kruppa
, 
Tatyana Viktorovna Leshina 2
Tatyana Viktorovna Leshina
10.1070/MC1991v001n04ABEH000088
Published 1991-12-31
Communication , Volume 1, Issue 4, 143-145
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Egorov M. P. et al. 1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 143-145.
GOST all authors (up to 50) Copy
Egorov M. P., Ezhova M. B., Kolesnikov S. P., Nefedov O. M., Taraban M. B., Kruppa A. I., Leshina T. V. 1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 143-145.
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TY - JOUR
DO - 10.1070/MC1991v001n04ABEH000088
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000088
TI - 1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond
T2 - Mendeleev Communications
AU - Egorov, Mikhail Petrovich
AU - Ezhova, Maria Borisovna
AU - Kolesnikov, Stanislav Petrovich
AU - Nefedov, Oleg Matveevich
AU - Taraban, Mark Borisovich
AU - Kruppa, Alexander Ivanovich
AU - Leshina, Tatyana Viktorovna
PY - 1991
DA - 1991/12/31
PB - Mendeleev Communications
SP - 143-145
IS - 4
VL - 1
ER -
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@article{1991_Egorov,
author = {Mikhail Petrovich Egorov and Maria Borisovna Ezhova and Stanislav Petrovich Kolesnikov and Oleg Matveevich Nefedov and Mark Borisovich Taraban and Alexander Ivanovich Kruppa and Tatyana Viktorovna Leshina},
title = {1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000088},
number = {4},
pages = {143--145},
doi = {10.1070/MC1991v001n04ABEH000088}
}
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Egorov, Mikhail Petrovich, et al. “1H CIDNP Study of the Addition Reaction of Me2E (E = Si,Ge) to a Carbon≡Carbon Triple Bond.” Mendeleev Communications, vol. 1, no. 4, Dec. 1991, pp. 143-145. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000088.

Abstract

Addition of Me2E (E = Si.Ge) to the triple bond of 3,3,6,6-tetramethyl-1-thiacyclohept-4-yne proceeds in a nonconcerted way via a 1,3-biradical intermediate; the first experimental evidence of the participation of an excited triplet Me2E species in a chemical reaction has been obtained.

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