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Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction

Grzegorz Schroeder 1
Grzegorz Schroeder
Janusz Przybyl 1
Janusz Przybyl
Arnold Jarczewski 1
Arnold Jarczewski
Published 1991-12-31
CommunicationVolume 1, Issue 4, 138-138
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Schroeder G., Przybyl J., Jarczewski A. Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 138-138.
GOST all authors (up to 50) Copy
Schroeder G., Przybyl J., Jarczewski A. Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction // Mendeleev Communications. 1991. Vol. 1. No. 4. pp. 138-138.
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TY - JOUR
DO - 10.1070/MC1991v001n04ABEH000085
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000085
TI - Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction
T2 - Mendeleev Communications
AU - Schroeder, Grzegorz
AU - Przybyl, Janusz
AU - Jarczewski, Arnold
PY - 1991
DA - 1991/12/31
PB - Mendeleev Communications
SP - 138-138
IS - 4
VL - 1
ER -
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@article{1991_Schroeder,
author = {Grzegorz Schroeder and Janusz Przybyl and Arnold Jarczewski},
title = {Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000085},
number = {4},
pages = {138--138},
doi = {10.1070/MC1991v001n04ABEH000085}
}
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Schroeder, Grzegorz, et al. “Influence of Alkyl Groups in Substituted Tetramethylguanidines on the Rate Constants and Deuterium Isotope Effect for the E2 Elimination Reaction.” Mendeleev Communications, vol. 1, no. 4, Dec. 1991, pp. 138-138. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n04ABEH000085.

Abstract

The kinetics of the E2 elimination reaction of 1,1,1-trichloro-2,2-di(4-nitrophenyl)ethane promoted by substituted alkyltetramethylguanidine R-N=C(NMe2)2 (where R = H, Me, Et, Pri and But) are reported and the influence of alkyl groups on the kinetic isotope effects in tetrahydrofuran is discussed.

References

1.
The Kinetic Deuterium Isotope Effect of Proton Transfer Reactions in Solution
Sühnel J.
Isotopenpraxis Isotopes in Environmental and Health Studies, 1986
2.
10.1070/MC1991v001n04ABEH000085_bib2
Bancel
1976
3.
10.1070/MC1991v001n04ABEH000085_bib3
Bell
The Tunnel Effect in Chemistry, 1980
6.
Kinetics, isotope effects, and mechanism of the reaction of 1-nitro-1(4-nitrophenyl)alkanes with DBU in acetonitrile
Gałezowski W., Jarczewski A.
Journal of the Chemical Society Perkin Transactions 2, 1989
7.
Tunneling in a Proton Transfer. A Large Isotope Effect
Funderburk L., Lewis E.S.
Journal of the American Chemical Society, 1964
8.
Rates and isotope effects in the proton transfers from 2-nitropropane to pyridine bases
Lewis E.S., Funderburk L.
Journal of the American Chemical Society, 1967
10.
10.1070/MC1991v001n04ABEH000085_bib10
Stewart
Proton: Application to Organic Chemistry, 1985