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The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts

Derek H. R. Barton 1
Derek H. R. Barton
, 
Dario Doller 1
Dario Doller
, 
Yurii Vasil'evich Geletii 1
Yurii Vasil'evich Geletii
1 Department of Chemistry, Texas A and M University, College Station, TX, USA
10.1070/MC1991v001n03ABEH000070
Published 1991-09-30
Communication , Volume 1, Issue 3, 115-116
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Barton D. H. R., Doller D., Geletii Y. V. The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 115-116.
GOST all authors (up to 50) Copy
Barton D. H. R., Doller D., Geletii Y. V. The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 115-116.
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TY - JOUR
DO - 10.1070/MC1991v001n03ABEH000070
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000070
TI - The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts
T2 - Mendeleev Communications
AU - Barton, Derek H. R.
AU - Doller, Dario
AU - Geletii, Yurii Vasil'evich
PY - 1991
DA - 1991/09/30
PB - Mendeleev Communications
SP - 115-116
IS - 3
VL - 1
ER -
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@article{1991_Barton,
author = {Derek H. R. Barton and Dario Doller and Yurii Vasil'evich Geletii},
title = {The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000070},
number = {3},
pages = {115--116},
doi = {10.1070/MC1991v001n03ABEH000070}
}
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Barton, Derek H. R., et al. “The Efficient Oxidation of Alkanes by Hydrogen Peroxide in Pyridine Mixed Solvents Catalysed by Copper and Other Transition Metal Salts.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 115-116. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000070.

Abstract

The catalytic activity of CuII, FeIII, CoII, RuIII, NiII and other transition metal salts in the oxidation of cyclododecane by H2O2 was studied for several mixed solvent systems PyX−S−H2O = 2:1:0.09 (volume ratio), were PyX is pyridine (Py) or substituted pyridines, and S = MeCN, Bu’OH or acetone; the highest yield, ca. 25% of alkane conversion and 10% efficiency for H2O2, was found for Py-MeCN mixtures.

References

1.
A new procedure for the oxidation of saturated hydrocarbons
Barton D.H., Gastiger M.J., Motherwell W.B.
Journal of the Chemical Society Chemical Communications, 1983
3.
Functionalization of saturated hydrocarbons. 14. Further studies on the mechanism of Gif-type systems
Barton D.H., Halley F., Ozbalik N., Schmitt M., Young E., Balavoine G.
Journal of the American Chemical Society, 1989
4.
D. H. R. Barton and D. Doller, Pure Appl. Chem., in the press.
5.
Oxidation of saturated hydrocarbons by hydrogen peroxide in pyridine solution catalysed by copper and iron perchlorates
Geletii Y.V., Lavrushko V.V., Lubimova G.V.
Journal of the Chemical Society Chemical Communications, 1988
6.
D. H. R. Barton, E. Csuhai, D. Doller and Yu. V. Geletii, Tetrahedron, in the press
8.
10.1070/MC1991v001n03ABEH000070_bib3
Barton
Nouv. J. Chim., 1986
9.
10.1070/MC1991v001n03ABEH000070_bib4_1
Geletii
Kinetika katal., 1985
10.
10.1070/MC1991v001n03ABEH000070_bib4_2
Geletii
Dokl. Akad. Nauk SSSR, 1986
11.
10.1070/MC1991v001n03ABEH000070_bib4_3
Geletii
The Role of Oxygen in Chemistry and Biochemistry, 1988
12.
D. H. R. Barton, D. Doller and Yu. V. Geletii, in preparation.
13.
10.1070/MC1991v001n03ABEH000070_bib6
Sheu
J. Am. Chem. Soc., 1990
14.
10.1070/MC1991v001n03ABEH000070_bib7
Nam
New J. Chem., 1989
15.
10.1070/MC1991v001n03ABEH000070_bib8
Moiseev
New J. Chem., 1989
16.
10.1070/MC1991v001n03ABEH000070_bib9
Barton
J. Chem. Soc., Chem. Commun., 1737