Home / Publications / First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−

First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−

Vassily Vasil'evich Krivykh 1
Vassily Vasil'evich Krivykh
, 
Elena Samuilovna Taits 1
Elena Samuilovna Taits
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
, 
Aleksandr Il'ich Yanovsky 1
Aleksandr Il'ich Yanovsky
10.1070/MC1991v001n03ABEH000063
Published 1991-09-30
Communication , Volume 1, Issue 3, 103-104
44
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Krivykh V. V. et al. First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4− // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 103-104.
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Krivykh V. V., Taits E. S., Petrovskii P. V., Struchkov Y. T., Yanovsky A. I. First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4− // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 103-104.
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TY - JOUR
DO - 10.1070/MC1991v001n03ABEH000063
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000063
TI - First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−
T2 - Mendeleev Communications
AU - Krivykh, Vassily Vasil'evich
AU - Taits, Elena Samuilovna
AU - Petrovskii, Pavel Vasil'evich
AU - Struchkov, Yuri Timofeevich
AU - Yanovsky, Aleksandr Il'ich
PY - 1991
DA - 1991/09/30
PB - Mendeleev Communications
SP - 103-104
IS - 3
VL - 1
ER -
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@article{1991_Krivykh,
author = {Vassily Vasil'evich Krivykh and Elena Samuilovna Taits and Pavel Vasil'evich Petrovskii and Yuri Timofeevich Struchkov and Aleksandr Il'ich Yanovsky},
title = {First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000063},
number = {3},
pages = {103--104},
doi = {10.1070/MC1991v001n03ABEH000063}
}
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Krivykh, Vassily Vasil'evich, et al. “First Example of the η3-Prop-2-ynyl Ligand; Synthesis and Reactivity of Cationic (η3-Prop-2-ynyl)arenedicarbonylmolybdenum Complexes; X-Ray Structure of [Mo(CO)2(η6-C6Me5H)(η3-HCCCH2)]+BF4−.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 103-104. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000063.

Abstract

A series of (η3-prop-2-ynyl)arenedicarbonylmolybdenum complexes with a novel η3-prop-2-ynyl ligand have been obtained, their structure has been established unambiguously by an X-ray diffraction study of a pentamethylbenzene derivative; the reactions of the η3-prop-2-ynyl derivatives with H2O and PPh3 yield complexes with 2-hydroxyallyl, 2-triphenyl phosphonioallyl and 1-triphenylphosphoionallene ligands.

References

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Cationic Areneallyldicarbonylchromium complexes
Nesmeyanov A.N., Krivykh V.V., Il'Minskaya E.S., Rybinskaya M.I.
Journal of Organometallic Chemistry, 1981
3.
The structure of dicarbonyl(η5-cyclopentadienyl)(η3-2-methylallyl)molybdenum(II), [Mo(C4H7)(C5H5)(CO)2]
Murrall N.W., Welch A.J.
Acta Crystallographica Section C Crystal Structure Communications, 1984
7.
10.1070/MC1991v001n03ABEH000063_bib7
Krivykh
Izv. Akad. Nauk SSSR, Ser. Khim., 1987