Home / Publications / Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2

Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2

Harry Adams 1
Harry Adams
, 
Neil A Bailey 1
Neil A Bailey
, 
Jeremy J Laskowski 1
Jeremy J Laskowski
, 
Christopher Ridgway 1
Christopher Ridgway
, 
Mark J Winter 1
Mark J Winter
10.1070/MC1991v001n03ABEH000061
Published 1991-09-30
Communication , Volume 1, Issue 3, 99-101
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Adams H. et al. Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 99-101.
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Adams H., Bailey N. A., Laskowski J. J., Ridgway C., Winter M. J. Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 99-101.
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TY - JOUR
DO - 10.1070/MC1991v001n03ABEH000061
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000061
TI - Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2
T2 - Mendeleev Communications
AU - Adams, Harry
AU - Bailey, Neil A
AU - Laskowski, Jeremy J
AU - Ridgway, Christopher
AU - Winter, Mark J
PY - 1991
DA - 1991/09/30
PB - Mendeleev Communications
SP - 99-101
IS - 3
VL - 1
ER -
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@article{1991_Adams,
author = {Harry Adams and Neil A Bailey and Jeremy J Laskowski and Christopher Ridgway and Mark J Winter},
title = {Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000061},
number = {3},
pages = {99--101},
doi = {10.1070/MC1991v001n03ABEH000061}
}
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Adams, Harry, et al. “Communal Products of Nucleophilic Attack at Iron Carbene and Photolysis of Iron Alkyl Complexes. Crystal Structures of CpFeCHS(CH2)2S⎴(CO)L (L = CO and PPh3) and CpFeCHS(CH2)2S⎴(CO)2.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 99-101. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000061.

Abstract

Treatment of the carbene CpFel(CO){=CHS(CH2)2S} with LiBEt3H or photolysis of the alkyl CpFe{CHS(CH2)2S}(CO)2 results in a mixture of CpFe{η2-CHS(CH2)2S}(CO), containing a labile Fe—S bond, and a dimeric species, the tricyclic diferradithiacyclohexane[CpFe{CHS(CH2)2S}(CO)]2.

References

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Journal of the Chemical Society Chemical Communications, 1986
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10.1070/MC1991v001n03ABEH000061_bib5
Collman
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Inorganic Chemistry, 1981