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On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites

Sandor M Nagy 1
Sandor M Nagy
, 
Eduard Arkad'evich Zubkov 1
Eduard Arkad'evich Zubkov
, 
Vyacheslav Gennad'evich Shubin 1
Vyacheslav Gennad'evich Shubin
, 
Aleksandr Gennad'evich Pelmenshchikov 2
Aleksandr Gennad'evich Pelmenshchikov
, 
Lidiya Alekseevna Vostrikova 2
Lidiya Alekseevna Vostrikova
, 
Kazimira Gavrilovna Ione 2
Kazimira Gavrilovna Ione
10.1070/MC1991v001n03ABEH000057
Published 1991-09-30
Communication , Volume 1, Issue 3, 94-95
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Nagy S. M. et al. On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 94-95.
GOST all authors (up to 50) Copy
Nagy S. M., Zubkov E. A., Shubin V. G., Pelmenshchikov A. G., Vostrikova L. A., Ione K. G. On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 94-95.
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TY - JOUR
DO - 10.1070/MC1991v001n03ABEH000057
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000057
TI - On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites
T2 - Mendeleev Communications
AU - Nagy, Sandor M
AU - Zubkov, Eduard Arkad'evich
AU - Shubin, Vyacheslav Gennad'evich
AU - Pelmenshchikov, Aleksandr Gennad'evich
AU - Vostrikova, Lidiya Alekseevna
AU - Ione, Kazimira Gavrilovna
PY - 1991
DA - 1991/09/30
PB - Mendeleev Communications
SP - 94-95
IS - 3
VL - 1
ER -
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@article{1991_Nagy,
author = {Sandor M Nagy and Eduard Arkad'evich Zubkov and Vyacheslav Gennad'evich Shubin and Aleksandr Gennad'evich Pelmenshchikov and Lidiya Alekseevna Vostrikova and Kazimira Gavrilovna Ione},
title = {On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000057},
number = {3},
pages = {94--95},
doi = {10.1070/MC1991v001n03ABEH000057}
}
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Nagy, Sandor M., et al. “On the Selectivity of the Bromination Reaction of Methylbenzenes on Zeolites.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 94-95. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000057.

Abstract

Experimental and quantum chemical data show the electrophilic agent involved in the bromination reaction of benzene and methylbenzenes on zeolite Na–Y to be more active than that on H–Y, antibatic changes in substrate and positional selectivity of the reaction being observed.

References

1.
Selective halogenation using molecular sieves
van Dijk J., van Daalen J.J., Paerels G.B.
Recueil des Travaux Chimiques des Pays-Bas, 2010
3.
Molecular sieves as catalysts for aromatic bromination
Zabicky J., Eger I., Galun A., Mhasalkar M.
Zeolites, 1987
5.
Selective para-bromination of toluene catalysed by Na-Y zeolite in the presence of an epoxide
de la Vega F., Sasson Y.
Journal of the Chemical Society Chemical Communications, 1989