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Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2

Natalya Yur'evna Kozitsyna 1
Natalya Yur'evna Kozitsyna
, 
Arkadii Moiseevich Ellern 1
Arkadii Moiseevich Ellern
, 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
, 
Yuri Timofeevich Struchkov 2
Yuri Timofeevich Struchkov
, 
Ilya Iosifovich Moiseev 1
Ilya Iosifovich Moiseev
10.1070/MC1991v001n03ABEH000056
Published 1991-09-30
Communication , Volume 1, Issue 3, 92-94
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Kozitsyna N. Y. et al. Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 92-94.
GOST all authors (up to 50) Copy
Kozitsyna N. Y., Ellern A. M., Antipin M. Y., Struchkov Y. T., Moiseev I. I. Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 92-94.
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TY - JOUR
DO - 10.1070/MC1991v001n03ABEH000056
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000056
TI - Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2
T2 - Mendeleev Communications
AU - Kozitsyna, Natalya Yur'evna
AU - Ellern, Arkadii Moiseevich
AU - Antipin, Mikhail Yuvenal'evich
AU - Struchkov, Yuri Timofeevich
AU - Moiseev, Ilya Iosifovich
PY - 1991
DA - 1991/09/30
PB - Mendeleev Communications
SP - 92-94
IS - 3
VL - 1
ER -
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@article{1991_Kozitsyna,
author = {Natalya Yur'evna Kozitsyna and Arkadii Moiseevich Ellern and Mikhail Yuvenal'evich Antipin and Yuri Timofeevich Struchkov and Ilya Iosifovich Moiseev},
title = {Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000056},
number = {3},
pages = {92--94},
doi = {10.1070/MC1991v001n03ABEH000056}
}
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Kozitsyna, Natalya Yur'evna, et al. “Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 92-94. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000056.

Abstract

The reaction of [Pd(OAc)2(PPh3)]2 with HCO2H includes the transfer of an O atom from the carboxylic ligand to the P atom and cleavage of the P—Ph bond accompanied by transfer of the Ph group from PPh3 ligand to the palladium atom; the structure of the complex formed, [Pd(μ-O2PPh2)(C6H5)(PPh3)]2, has been resolved by X-ray analysis.

References

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