Home / Publications / Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO₂(OC₂H₄OMe)₂ and Polymeric NaMoO₂(OC₂H₄OMe)₃

Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO₂(OC₂H₄OMe)₂ and Polymeric NaMoO₂(OC₂H₄OMe)₃

Vadim Germanovich Kessler ¹

Vadim Germanovich Kessler

Nataliya Yakovlevna Turova ¹

Nataliya Yakovlevna Turova

Andrei V Korolev ²

Andrei V Korolev

Aleksandr Il'ich Yanovsky ²

Aleksandr Il'ich Yanovsky

Yuri Timofeevich Struchkov ²

Yuri Timofeevich Struchkov

¹ Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

² A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1070/MC1991v001n03ABEH000054

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Published 1991-09-30

Communication , Volume 1, Issue 3, 89-91

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Kessler V. G. et al. Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 89-91.

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Kessler V. G., Turova N. Y., Korolev A. V., Yanovsky A. I., Struchkov Y. T. Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3 // Mendeleev Communications. 1991. Vol. 1. No. 3. pp. 89-91.

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TY - JOUR

DO - 10.1070/MC1991v001n03ABEH000054

UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000054

TI - Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3

T2 - Mendeleev Communications

AU - Kessler, Vadim Germanovich

AU - Turova, Nataliya Yakovlevna

AU - Korolev, Andrei V

AU - Yanovsky, Aleksandr Il'ich

AU - Struchkov, Yuri Timofeevich

PY - 1991

DA - 1991/09/30

PB - Mendeleev Communications

SP - 89-91

IS - 3

VL - 1

ER -

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@article{1991_Kessler,

author = {Vadim Germanovich Kessler and Nataliya Yakovlevna Turova and Andrei V Korolev and Aleksandr Il'ich Yanovsky and Yuri Timofeevich Struchkov},

title = {Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3},

journal = {Mendeleev Communications},

year = {1991},

volume = {1},

publisher = {Mendeleev Communications},

month = {Sep},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000054},

number = {3},

pages = {89--91},

doi = {10.1070/MC1991v001n03ABEH000054}

}

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Kessler, Vadim Germanovich, et al. “Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3.” Mendeleev Communications, vol. 1, no. 3, Sep. 1991, pp. 89-91. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n03ABEH000054.

Abstract

Reaction of MoO(OEt)₄ with an excess of methoxyethanol leads to the formation of MoO(OC₂H₄OMe)₄, which decomposes to give complex MoO₂(OC₂H₄OMe)₂ 1, an X-ray structural study of which shows that its crystals are constructed of monomeric molecules with both methoxyethoxide groups forming chelate rings around the molybdenum atoms; interaction of 1 with NaOC₂H₄OMe in methoxyethanol results in the formation of a complex NaMoO₂(OC₂H₄OMe)₃ 2, whose polymeric structure, established by X-ray analysis, contains a planar tetranuclear fragment analoguous to that found in Ti₄(OMe)₁₆.

References

10.1070/MC1991v001n03ABEH000054_bib1

Kessler

Zh. Obshch. Khim., 1990

10.1070/MC1991v001n03ABEH000054_bib2

Turova

Zh. Obshch. Khim., 1990

10.1070/MC1991v001n03ABEH000054_bib3

Gerr

Kristallografiya, 1983

G. M. Sheldrick, SHELXTL PC Reference Manual, 1990.

10.1070/MC1991v001n03ABEH000054_bib5

Porai-Koshits

Kristallokhimiya i stereokhimiya koordinatsionnykh soedinenii molibdena, (Crystal chemistry and stereochemistry of coordination compounds of molybdenum), 1974