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Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites

Aleksandr Nikolaevich Zakharov 1
Aleksandr Nikolaevich Zakharov
10.1070/MC1991v001n02ABEH000049
Published 1991-06-30
Communication , Volume 1, Issue 2, 80-81
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Zakharov A. N. Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 80-81.
GOST all authors (up to 50) Copy
Zakharov A. N. Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 80-81.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000049
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000049
TI - Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites
T2 - Mendeleev Communications
AU - Zakharov, Aleksandr Nikolaevich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 80-81
IS - 2
VL - 1
ER -
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@article{1991_Zakharov,
author = {Aleksandr Nikolaevich Zakharov},
title = {Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000049},
number = {2},
pages = {80--81},
doi = {10.1070/MC1991v001n02ABEH000049}
}
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Zakharov, Aleksandr Nikolaevich. “Complexes of Transition Metals in Zeolites. Activation of Hydrogenation Functions of Phthalocyanine FeII Complexes by Zeolites.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 80-81. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000049.

Abstract

The liquid-phase hydrogenation of toluene by dihydrogen in the presence of zeolite-included FeII phthalocyanine has been studied, (effective energy of activation and pre-exponential factor 28 ± 2 kJ mol−1 and 10.3 × 105 g mol−1 s−1, respectively) and it has been suggested that the zeolite matrix takes part in the activation of the substrate via hydrogen bonding with inner atoms of the large cavity of the zeolite.

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