Home / Publications / Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond

Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond

Valery Nikolaevich Kalinin 1
Valery Nikolaevich Kalinin
, 
Ilya Aleksandrovich Cherepanov 1
Ilya Aleksandrovich Cherepanov
, 
Sergey Konstantinovich Moiseev 1
Sergey Konstantinovich Moiseev
, 
Andrey S Botsanov 1
Andrey S Botsanov
, 
Yuri Timofeevich Struchkov 1
Yuri Timofeevich Struchkov
10.1070/MC1991v001n02ABEH000047
Published 1991-06-30
Communication , Volume 1, Issue 2, 77-78
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Kalinin V. N. et al. Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 77-78.
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Kalinin V. N., Cherepanov I. A., Moiseev S. K., Botsanov A. S., Struchkov Y. T. Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 77-78.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000047
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000047
TI - Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond
T2 - Mendeleev Communications
AU - Kalinin, Valery Nikolaevich
AU - Cherepanov, Ilya Aleksandrovich
AU - Moiseev, Sergey Konstantinovich
AU - Botsanov, Andrey S
AU - Struchkov, Yuri Timofeevich
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 77-78
IS - 2
VL - 1
ER -
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@article{1991_Kalinin,
author = {Valery Nikolaevich Kalinin and Ilya Aleksandrovich Cherepanov and Sergey Konstantinovich Moiseev and Andrey S Botsanov and Yuri Timofeevich Struchkov},
title = {Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000047},
number = {2},
pages = {77--78},
doi = {10.1070/MC1991v001n02ABEH000047}
}
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Kalinin, Valery Nikolaevich, et al. “Reactivity of α-Metallated Alkylarene Tricarbonylchromium Complexes. Preparation, Properties and X-Ray Crystal Structure of (η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3, a Novel Complex with a Palladium–Chromium σ–Bond.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 77-78. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000047.

Abstract

The reaction of [Cr(η6-PhCH2ZnCl)(CO)3] 1 with [{Pd(η3-C3H5)Cl}2] 2 in tetrahydrofuran yields a novel complex [(η3-C3H5)Pd(CH2Ph-η6)–C⎴r(CO)3] 3 with a Pd–Cr bond; the reaction of 3 with Phl leads to [Cr(CO)3(η6-PhCH2Ph)].

References

1.
10.1070/MC1991v001n02ABEH000047_bib1
Kalinin
Metalloorg. Khim., 1991