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Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration

Rashid Gasanovich Gasanov 1
Rashid Gasanovich Gasanov
, 
Tamara Trofimovna Vasil'eva 1
Tamara Trofimovna Vasil'eva
, 
Sergei I Gapusenko 1
Sergei I Gapusenko
10.1070/MC1991v001n02ABEH000042
Published 1991-06-30
Communication , Volume 1, Issue 2, 70-71
5
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Gasanov R. G., Vasil'eva T. T., Gapusenko S. I. Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 70-71.
GOST all authors (up to 50) Copy
Gasanov R. G., Vasil'eva T. T., Gapusenko S. I. Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration // Mendeleev Communications. 1991. Vol. 1. No. 2. pp. 70-71.
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TY - JOUR
DO - 10.1070/MC1991v001n02ABEH000042
UR - https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000042
TI - Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration
T2 - Mendeleev Communications
AU - Gasanov, Rashid Gasanovich
AU - Vasil'eva, Tamara Trofimovna
AU - Gapusenko, Sergei I
PY - 1991
DA - 1991/06/30
PB - Mendeleev Communications
SP - 70-71
IS - 2
VL - 1
ER -
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@article{1991_Gasanov,
author = {Rashid Gasanovich Gasanov and Tamara Trofimovna Vasil'eva and Sergei I Gapusenko},
title = {Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration},
journal = {Mendeleev Communications},
year = {1991},
volume = {1},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000042},
number = {2},
pages = {70--71},
doi = {10.1070/MC1991v001n02ABEH000042}
}
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Gasanov, Rashid Gasanovich, et al. “Mechanism and Rate Constant for Rearrangement of Radicals PhCH2CH2CH(CF3)CH2ĊHCF3 to PhĊHCH2CH(CF3)CH2CH2CF3 with 1,5-Hydrogen Migration.” Mendeleev Communications, vol. 1, no. 2, Jun. 1991, pp. 70-71. https://mendcomm.colab.ws/publications/10.1070/MC1991v001n02ABEH000042.

Abstract

The intramolecular mechanism of the rearrangement of radicals PhCH2CH2CH(CF3)CH2ĊHCF3 (R1) to PhĊHCH2CH(CF3)CH2CH2CF3 (R2) with 1,5-hydrogen migration has been elucidated using EPR spectroscopy and the rate constant of isomerization kis = 5.0(± 0.3) x 104 s–1 at 22 °C has been determined.

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